The present invention relates to a multilayer structure at least an outer layer and an inner layer which contain a polypropylene resin as a main component, a barrier resin layer containing an ethylene-vinyl alcohol copolymer as a main component, and a metal deposited layer containing aluminum as a main component; a packaging material for a retort therewith; a method for recovering the multilayer structure; and a recovered composition comprising a recovered material of the multilayer structure. There is provided a multilayer structure exhibiting excellent recyclability and excellent appearance, gas barrier ability and shading performance both before and after retorting treatment, and a packaging material for a retort therewith.