An electrochemical cell includes an anode comprising a first anode metal, an anode current collector, a cathode comprising a first cathode metal, a cathode current collector, and an electrolyte layer between the anode and the cathode. The electrolyte layer comprises a mesoporous material of polymer or glass and a salt electrolyte filling pores of the mesoporous material, wherein the pores are interconnected and the salt electrolyte is a salt of the first anode metal.