A honeycomb structure 20 according to the present invention includes: a honeycomb structure portion 10 including: an outer peripheral wall 12; a partition wall 13 arranged on an inner side of the outer peripheral wall 12, the partition wall 13 defining a plurality of cells 16 each extending from one end face to other end face to form a flow path; and a pair of electrode layers 14a, 14b arranged on a surface of the outer peripheral wall 12 of the honeycomb structure portion 10, the pair of electrode layers 14 being provided so as to face each other across a central axis of the honeycomb structure portion 10. The honeycomb structure portion 10 is made of ceramics having an NTC property, and the pair of electrode layers are made of a material having a PTC property.