To improve the capacity of an all-solid-state battery, a method of manufacturing an all-solid-state battery having a cathode that contains sulfur include: performing initial charge and discharge separately at least in three cycles until a capacity of the battery reaches a design capacity, wherein a charge discharge capacity in a first cycle is at most 30% of the design capacity, and charge and discharge in a second cycle and after are performed, so that a charge discharge capacity in an n-th cycle is increased at least 1.15 times as much as a charge discharge capacity in an (n-1)-th cycle.