Provided are a method for preparing a gel composite material with a piezoelectric property, and the gel composite material and use thereof, which belongs to the field of intelligent road traffic. In the method, titanium-containing blast furnace slag and metal oxides (PbO and ZrO2) are sufficiently and uniformly mixed, an obtained mixture is calcined under a certain thermal system, on the theoretical basis of mineral-phase reconstruction-synergistic regulation of all valuable components, and the mixture is cooled to a room temperature with a furnace to obtain the gel composite material with a piezoelectric property.