An anti-reflection energy-saving film structure and a method for manufacturing the same are provided. The anti-reflection energy-saving film structure includes a carrier layer, a barrier layer, an anti-reflection layer, and an adhesive layer. The carrier layer has a first surface and a second surface. The barrier layer is arranged on the first surface of the carrier layer. The anti-reflection layer is arranged on the second surface of the carrier layer. The anti-reflection layer has a plurality of moth-eye structures. The plurality of moth-eye structures cover 60% to 100% of a total area of the second surface, and a top of each of the plurality of moth-eye structures is conical or arc-shaped. The adhesive layer is arranged on the barrier layer.