The disclosure relates to compositions comprising (a) at least one polyphenol; (b) at least one film former; (c) at least one emulsifier; (d) at least one fatty compound; and (e) at least one solvent. Optionally, the compositions may further comprise at least one oil, at least one humectant, and/or at least one fatty acid. The compositions can be used for styling hair, for example temporarily straightening the hair and/or for reducing frizz of hair. The disclosure also relates to methods of using the compositions to style hair, straighten hair, and/or reduce frizz of hair.