- 专利标题: COATING COMPOSITION WITH IMPROVED BLOCK AND HUMIDITY RESISTANCE, DIRECT TO METAL ADHERENCE AND LOW VOC CONTENT
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申请号: US18022766申请日: 2021-08-26
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公开(公告)号: US20230312972A1公开(公告)日: 2023-10-05
- 发明人: Yuting LI , Robert P. EISENHARDT , Wenjun WU , Michael DREWERY , Jeffrey P. ARDENT
- 申请人: Arkema Inc.
- 申请人地址: US PA King of Prussia
- 专利权人: Arkema Inc.
- 当前专利权人: Arkema Inc.
- 当前专利权人地址: US PA King of Prussia
- 国际申请: PCT/US21/47755 2021.08.26
- 进入国家日期: 2023-02-23
- 主分类号: C09D147/00
- IPC分类号: C09D147/00 ; C08F220/10 ; C08F2/44
摘要:
Multi-stage polymeric particles are prepared as a water-borne emulsion, including a first-formed lower Tg soft stage and a second-formed higher Tg hard stage. The polymeric particles include, in both stages: one or more free radical polymerizable ethylenically unsaturated monomers; 0 to 3 wt % of free radical polymerizable surfactant monomer; 0 to 4 wt % of free radical poly-merizable monomer having a beta dicarbonyl functionality; 0 to 2 wt % of monomer selected from acrylamide, diacetone acrylamide, 2-hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylates, and hydroxybutyl (meth)acrylates and mixtures thereof; 0-1.9 wt % of free radical polymerizable polyethylenically unsaturated monomers; 0.1 to 1.9% of free radical polymerizable monomer containing phosphorus acid or a salt thereof in the first stage, and 0.1 to 5 wt % of a free radical polymerizable monomer containing phosphorus acid or salt thereof in the second stage. Multi-stage polymeric-particle-based-resin is formulated into direct to metal coatings, having good block, corrosion and excellent humidity resistance.
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