- 专利标题: SHELF LIFE- AND TRANSPORT STABILIZERS FOR POLYMERIZABLE COMPOUNDS
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申请号: US17780573申请日: 2020-11-23
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公开(公告)号: US20230348694A1公开(公告)日: 2023-11-02
- 发明人: Sylke HAREMZA , Friedrich-Georg MARTIN , Doris KREMZOW-GRAW , Rebecca SURE , Juergen ROMEIS , Korwin SCHELKLE , Friederike FLEISCHHAKER , Jan Niclas GORGES
- 申请人: BASF SE
- 申请人地址: DE Ludwigshafen am Rhein
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen am Rhein
- 优先权: EP 212189.5 2019.11.28
- 国际申请: PCT/EP2020/083014 2020.11.23
- 进入国家日期: 2022-05-27
- 主分类号: C08K5/3445
- IPC分类号: C08K5/3445 ; C08F220/06 ; C08F220/14 ; C08F220/18
摘要:
A mixture comprising one or more compounds of the general formula (II)
where
R6 is H, C1 to C20 alkyl, where C1 to C20 alkyl comprises straight-chain or branched C1 to C20 alkyl groups or cyclic C3 to C20 alkyl groups, alkanoyl having C1 to C8 alkyl, where C1 to C8 alkyl comprises straight-chain or branched C1 to C8 alkyl groups or cyclic C3 to C8 alkyl groups, cyanophenyl, 2-chlorophenyl, 3-chlorophenyl, 4-chlorophenyl, 2,4-dichlorophenyl, 3,4-dichlorophenyl, 2-bromophenyl, 3-bromophenyl, 4-bromophenyl, 2-methylphenyl, 3-methylphenyl, 4-methylphenyl, dimethylphenyl, such as 3,4-dimethylphenyl, 2-methoxyphenyl, 3-methoxyphenyl, 4-methoxyphenyl, 2-ethylphenyl, 3-ethylphenyl, 4-ethylphenyl, 2-ethoxyphenyl, 3-ethoxyphenyl, 4-ethoxyphenyl, 4-isopropylphenyl, benzyl, 2-pyridyl, 3-pyridyl, 4-pyridyl, (carboxymethyl)phenyl, in which the carboxyl group may also be esterified with C1 to C6 alkyl, where C1 to C6 alkyl comprises straight-chain or branched C1 to C6 alkyl groups or cyclic C3 to C6 alkyl groups, (N,N-dimethylsulfonamido)phenyl, sulfonamidophenyl or 4-isopropoxyphenyl,
R7 is H, C1 to C20 alkyl, where C1 to C20 alkyl comprises straight-chain or branched C1 to C20 alkyl groups or cyclic C3 to C20 alkyl groups, phenyl, carboxylic esters having C1 to C8 alkyl, where C1 to C8 alkyl comprises straight-chain or branched C1 to C6 alkyl groups or cyclic C3 to C8 alkyl groups, alkanoyl having C1 to C8 alkyl, where C1 to C8 alkyl comprises straight-chain or branched C1 to C8 alkyl groups or cyclic C3 to C8 alkyl groups, cyanophenyl, 2-chlorophenyl, 3-chlorophenyl, 4-chlorophenyl, 2,4-dichlorophenyl, 3,4-dichlorophenyl, 2-bromophenyl, 3-bromophenyl, 4-bromophenyl, 2-methylphenyl, 3-methylphenyl, 4-methylphenyl, dimethylphenyl, such as 3,4-dimethylphenyl, 2-methoxyphenyl, 3-methoxyphenyl, 4-methoxyphenyl, 2-ethylphenyl, 3-ethylphenyl, 4-ethylphenyl, 2-ethoxyphenyl, 3-ethoxyphenyl, 4-ethoxyphenyl, 4-isopropylphenyl, benzyl, 2-pyridyl, 3-pyridyl, 4-pyridyl, (carboxymethyl)phenyl, in which the carboxyl group may also be esterified with C1 to C6 alkyl, where C1 to C6 alkyl comprises straight-chain or branched C1 to C6 alkyl groups or cyclic C3 to C6 alkyl groups, (N,N-dimethylsulfonamido)phenyl, sulfonamidophenyl or 4-isopropoxyphenyl, and
R8 is H, C1 to C20 alkyl, where C1 to C20 alkyl comprises straight-chain or branched C1 to C20 alkyl groups or cyclic C3 to C20 alkyl groups, phenyl, carboxylic esters having C1 to C8 alkyl, where C1 to C8 alkyl comprises straight-chain or branched C1 to C8 alkyl groups or cyclic C3 to C8 alkyl groups, alkanoyl having C1 to C8 alkyl, where C1 to C8 alkyl comprises straight-chain or branched C1 to C8 alkyl groups or cyclic C3 to C8 alkyl groups, cyanophenyl, 2-chlorophenyl, 3-chlorophenyl, 4-chlorophenyl, 2,4-dichlorophenyl, 3,4-dichlorophenyl, 2-bromophenyl, 3-bromophenyl, 4-bromophenyl, 2-methylphenyl, 3-methylphenyl, 4-methylphenyl, dimethylphenyl, such as 3,4-dimethylphenyl, 2-methoxyphenyl, 3-methoxyphenyl, 4-methoxyphenyl, 2-ethylphenyl, 3-ethylphenyl, 4-ethylphenyl, 2-ethoxyphenyl, 3-ethoxyphenyl, 4-ethoxyphenyl, 4-isopropylphenyl, benzyl, 2-pyridyl, 3-pyridyl, 4-pyridyl, (carboxymethyl)phenyl, in which the carboxyl group may also be esterified with C1 to C6 alkyl, where C1 to C6 alkyl comprises straight-chain or branched C1 to C6 alkyl groups or cyclic C3 to C6 alkyl groups, (N,N-dimethylsulfonamido)phenyl, sulfonamidophenyl or 4-isopropoxyphenyl,
and (meth)acrylic acid and/or C1 to C8 alkyl (meth)acrylates.
where
R6 is H, C1 to C20 alkyl, where C1 to C20 alkyl comprises straight-chain or branched C1 to C20 alkyl groups or cyclic C3 to C20 alkyl groups, alkanoyl having C1 to C8 alkyl, where C1 to C8 alkyl comprises straight-chain or branched C1 to C8 alkyl groups or cyclic C3 to C8 alkyl groups, cyanophenyl, 2-chlorophenyl, 3-chlorophenyl, 4-chlorophenyl, 2,4-dichlorophenyl, 3,4-dichlorophenyl, 2-bromophenyl, 3-bromophenyl, 4-bromophenyl, 2-methylphenyl, 3-methylphenyl, 4-methylphenyl, dimethylphenyl, such as 3,4-dimethylphenyl, 2-methoxyphenyl, 3-methoxyphenyl, 4-methoxyphenyl, 2-ethylphenyl, 3-ethylphenyl, 4-ethylphenyl, 2-ethoxyphenyl, 3-ethoxyphenyl, 4-ethoxyphenyl, 4-isopropylphenyl, benzyl, 2-pyridyl, 3-pyridyl, 4-pyridyl, (carboxymethyl)phenyl, in which the carboxyl group may also be esterified with C1 to C6 alkyl, where C1 to C6 alkyl comprises straight-chain or branched C1 to C6 alkyl groups or cyclic C3 to C6 alkyl groups, (N,N-dimethylsulfonamido)phenyl, sulfonamidophenyl or 4-isopropoxyphenyl,
R7 is H, C1 to C20 alkyl, where C1 to C20 alkyl comprises straight-chain or branched C1 to C20 alkyl groups or cyclic C3 to C20 alkyl groups, phenyl, carboxylic esters having C1 to C8 alkyl, where C1 to C8 alkyl comprises straight-chain or branched C1 to C6 alkyl groups or cyclic C3 to C8 alkyl groups, alkanoyl having C1 to C8 alkyl, where C1 to C8 alkyl comprises straight-chain or branched C1 to C8 alkyl groups or cyclic C3 to C8 alkyl groups, cyanophenyl, 2-chlorophenyl, 3-chlorophenyl, 4-chlorophenyl, 2,4-dichlorophenyl, 3,4-dichlorophenyl, 2-bromophenyl, 3-bromophenyl, 4-bromophenyl, 2-methylphenyl, 3-methylphenyl, 4-methylphenyl, dimethylphenyl, such as 3,4-dimethylphenyl, 2-methoxyphenyl, 3-methoxyphenyl, 4-methoxyphenyl, 2-ethylphenyl, 3-ethylphenyl, 4-ethylphenyl, 2-ethoxyphenyl, 3-ethoxyphenyl, 4-ethoxyphenyl, 4-isopropylphenyl, benzyl, 2-pyridyl, 3-pyridyl, 4-pyridyl, (carboxymethyl)phenyl, in which the carboxyl group may also be esterified with C1 to C6 alkyl, where C1 to C6 alkyl comprises straight-chain or branched C1 to C6 alkyl groups or cyclic C3 to C6 alkyl groups, (N,N-dimethylsulfonamido)phenyl, sulfonamidophenyl or 4-isopropoxyphenyl, and
R8 is H, C1 to C20 alkyl, where C1 to C20 alkyl comprises straight-chain or branched C1 to C20 alkyl groups or cyclic C3 to C20 alkyl groups, phenyl, carboxylic esters having C1 to C8 alkyl, where C1 to C8 alkyl comprises straight-chain or branched C1 to C8 alkyl groups or cyclic C3 to C8 alkyl groups, alkanoyl having C1 to C8 alkyl, where C1 to C8 alkyl comprises straight-chain or branched C1 to C8 alkyl groups or cyclic C3 to C8 alkyl groups, cyanophenyl, 2-chlorophenyl, 3-chlorophenyl, 4-chlorophenyl, 2,4-dichlorophenyl, 3,4-dichlorophenyl, 2-bromophenyl, 3-bromophenyl, 4-bromophenyl, 2-methylphenyl, 3-methylphenyl, 4-methylphenyl, dimethylphenyl, such as 3,4-dimethylphenyl, 2-methoxyphenyl, 3-methoxyphenyl, 4-methoxyphenyl, 2-ethylphenyl, 3-ethylphenyl, 4-ethylphenyl, 2-ethoxyphenyl, 3-ethoxyphenyl, 4-ethoxyphenyl, 4-isopropylphenyl, benzyl, 2-pyridyl, 3-pyridyl, 4-pyridyl, (carboxymethyl)phenyl, in which the carboxyl group may also be esterified with C1 to C6 alkyl, where C1 to C6 alkyl comprises straight-chain or branched C1 to C6 alkyl groups or cyclic C3 to C6 alkyl groups, (N,N-dimethylsulfonamido)phenyl, sulfonamidophenyl or 4-isopropoxyphenyl,
and (meth)acrylic acid and/or C1 to C8 alkyl (meth)acrylates.
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