A decolorization method of a polyester fabric includes: providing a polyester fabric, in which the polyester fabric is a dyed polyester fabric and the polyester fabric is adhered with a dye and has a first L value; providing a first decolorizing solution and a second decolorizing solution, in which the first decolorizing solution contains a reductant and the second decolorizing solution contains an oxidant; and performing a decolorization process which includes: using one of the first decolorizing solution and the second decolorizing solution to decolorize one portion of the dye and using another one of the first decolorizing solution and the second decolorizing solution to decolorize another portion of the dye, so that a color of the dye is removed and the polyester fabric is white in color and has a second L value that is greater than the first L value.