The present disclosure provides an electrode for use in an electrochemical cell that cycles lithium ions. The electrode has a thickness greater than or equal to about 50 micrometers to less than or equal to about 500 micrometers and includes an electroactive material, a polytetrafluoroethylene-based binder, and a porous crystalline material additive. For example, the electrode may include greater than or equal to about 0.01 wt. % to less than or equal to about 20 wt. % of the porous crystalline material additive, and greater than or equal to about 0.01 wt. % to less than or equal to about 20 wt. % of the polytetrafluoroethylene-based binder. The porous crystalline material additive is selected from the group consisting of: metal-organic frameworks (MOFs), covalent-organic frameworks (COFs), and combinations thereof.