To provide a steel sheet with a tensile strength of 1310 MPa or more that can achieve excellent press formability in a steel having a martensite-dominant microstructure with excellent delayed fracture resistance properties. Disclosed is a steel sheet including: a chemical composition containing, by mass %, C: 0.12-0.40%, Si: 1.5% or less, Mn: 1.7% or less, P: 0.05% or less, S: 0.010% or less, sol.Al: 1.00% or less, N: 0.010% or less, Ti: 0.002-0.080%, and B: 0.0002-0.0050%, with the balance being Fe and inevitable impurities; a metallic structure in which an area ratio of martensite to an entire microstructure is 95% or more, and a ratio LS/LB satisfies a predetermined formula (1), where LS denotes a length of a sub-block boundary and LB denotes a length of a block boundary; and a tensile strength of 1310 MPa or more.