A method for a removal of HA from water is provided, including using PMS as an oxidant, using VI or UV as an activation source, and adding a MIEX resin into the water for a reaction. By applying the method, irradiated by the visible light, a VI/MIEX/PMS system is coupling to strengthen adsorption process, thereby realizing a relatively high removal effect on the HA; therefore, the VI/MIEX/PMS system can be suitable for a large-scale environment performed by water treatment, and a removal efficiency thereof on HA can reach 60% or above. Moreover, irradiated by the ultraviolet light, a UV/MIEX/PMS system can be suitable for small and medium-sized environment performed by rapid water treatment, and can cope with sudden HA pollution of water source in a medium and small range, and a removal efficiency thereof on HA can reach 90% or above.