An organic iodine trapping apparatus and method efficiently traps organic iodine in a nuclear reactor container vessel. A liquid vessel contains a non-volatile liquid (e.g., ionic liquid or interfacial active agent solution) capable of decomposing organic iodine. An introduction pipe introduces a fluid containing organic iodine in the nuclear reactor container vessel to the non-volatile liquid. The non-volatile liquid is heated by heat in the nuclear reactor container vessel or reaction heat of the fluid in the nuclear reactor container vessel. Then, the trapping apparatus decomposes and traps the organic iodine. The organic iodine trapping method includes heating a non-volatile liquid capable of decomposing organic iodine by heat in the nuclear reactor container vessel or reaction heat of fluid in the nuclear reactor container vessel; making the fluid containing organic iodine pass through the heated non-volatile liquid; and decomposing and trapping the organic iodine in the non-volatile liquid.