公开(公告)号：US20220139586A1

公开(公告)日：2022-05-05

申请号：US17433271

申请日：2020-01-21

申请人： HITACHI-GE NUCLEAR ENERGY, LTD.

发明人： Sohei FUKUI ,  Motoi TANAKA ,  Masaaki TANAKA ,  Fumio TOTSUKA ,  Tomoharu HASHIMOTO ,  Kazuo TOMINAGA

IPC分类号： G21F9/02 ,  B01D53/70 ,  G21C13/02 ,  B01D53/02

摘要： As an organic iodine remover that removes organic iodine in a containment vessel of a nuclear reactor, an organic agent (for example, an ionic liquid, an interfacial active agent, a quaternary salt, or a phase transfer catalyst) having a function of dissolving and decomposing the organic iodine and retaining iodine is used. The organic iodine remover is a substance composed of a cation and an anion. The organic iodine remover is, in particular, an organic iodine remover in which, in a structure of the cation of the organic agent, carbon or oxygen is bonded to, via a single bond, to a phosphorus element, a sulfur element or a nitrogen element, the number of carbon chains is 2 or more, and an anionic structure is configured with a substance with high nucleophilicity. By using such an organic agent, the organic iodine is removed with an efficiency of 99% or more.

公开(公告)号：US20240233967A1

公开(公告)日：2024-07-11

申请号：US18616833

申请日：2024-03-26

申请人： HITACHI-GE NUCLEAR ENERGY, LTD.

发明人： Sohei FUKUI ,  Motoi TANAKA ,  Masaaki TANAKA ,  Fumio TOTSUKA ,  Tomoharu HASHIMOTO ,  Kazuo TOMINAGA

IPC分类号： G21C9/004 ,  G21C13/02 ,  G21F9/02 ,  G21F9/06

CPC分类号： G21C9/004 ,  G21C13/022 ,  G21F9/02 ,  G21F9/06

摘要： An organic iodine trapping apparatus and method efficiently traps organic iodine in a nuclear reactor container vessel. A liquid vessel contains a non-volatile liquid (e.g., ionic liquid or interfacial active agent solution) capable of decomposing organic iodine. An introduction pipe introduces a fluid containing organic iodine in the nuclear reactor container vessel to the non-volatile liquid. The non-volatile liquid is heated by heat in the nuclear reactor container vessel or reaction heat of the fluid in the nuclear reactor container vessel. Then, the trapping apparatus decomposes and traps the organic iodine. The organic iodine trapping method includes heating a non-volatile liquid capable of decomposing organic iodine by heat in the nuclear reactor container vessel or reaction heat of fluid in the nuclear reactor container vessel; making the fluid containing organic iodine pass through the heated non-volatile liquid; and decomposing and trapping the organic iodine in the non-volatile liquid.

公开(公告)号：US20230032273A1

公开(公告)日：2023-02-02

申请号：US17787105

申请日：2020-12-01

申请人： HITACHI-GE NUCLEAR ENERGY, LTD.

发明人： Sohei FUKUI ,  Motoi TANAKA ,  Kazuo TOMINAGA ,  Masaaki TANAKA ,  Fumio TOTSUKA ,  Tomoharu HASHIMOTO

IPC分类号： B01D53/14 ,  B01J20/22 ,  G21F9/02

摘要： An organic iodine remover is a remover for removing organic iodine and is a substance composed of a cation and an anion, and the cation (for example, a phosphonium cation, an ammonium cation, or a sulfonium cation) has a molecular structure in which an electron donating group (for example, a phosphino group, an amino group, a sulfanyl group, a hydroxy group, or an alkoxy group) is bonded to a phosphorus atom, a nitrogen atom or a sulfur atom. An organic iodine removing apparatus includes: a vessel into which the organic iodine remover for removing the organic iodine is charged; and introduction pipes through which a fluid containing organic iodine is introduced into the organic iodine remover.

公开(公告)号：US20210316248A1

公开(公告)日：2021-10-14

申请号：US17223078

申请日：2021-04-06

申请人： Hitachi-GE Nuclear Energy, Ltd.

发明人： Sohei FUKUI ,  Kazushige ISHIDA ,  Kazuo TOMINAGA ,  Motoi TANAKA ,  Tomoharu HASHIMOTO

IPC分类号： B01D53/14 ,  B01D53/18 ,  B01D53/70 ,  B01D53/78 ,  B01D53/79

摘要： There is provided an organic iodine trapping apparatus that can efficiently trap an organic iodine without using complicated or large equipment. An organic iodine trapping apparatus 30 is an apparatus that traps an organic iodine, including: a trapping vessel 1 through which gas containing an organic iodine is passed; an organic iodine remover 2 (Example: trihexyl (tetradecyl) phosphonium chloride, or the like) that is disposed in or injected into the trapping vessel 1 and decomposes the organic iodine; and a trapping material 3 that is disposed in or injected into the trapping vessel 1 and traps iodine ions generated by decomposition of the organic iodine, in which the trapping material 3 is a metal (Example: silver or the like) or a metal compound (Example: silver chloride, silver oxide, or the like).