An electrochemical apparatus includes a positive electrode, a negative electrode, a separator, and an electrolyte, where the positive electrode includes a positive electrode current collector, a positive electrode active substance layer, and a conductive coating disposed between the positive electrode current collector and the positive electrode active substance layer; the electrolyte includes a first fluorine-containing metal salt, where the first fluorine-containing metal salt includes at least one of fluorine-containing sulfonimide lithium salts; and the electrochemical apparatus satisfies the following relationship: 0.1≤X/d≤105, where X g/m2 is mass per unit area of fluorine-containing sulfonimide lithium salt contained in the electrochemical apparatus on one surface of the positive electrode current collector, and d μm is thickness of the conductive coating on one surface of the positive electrode current collector.