发明授权
US3553291A Process of curing unsaturated polyester resins using acetylenic diperesters
失效
使用乙酰基DIPERESTER固化不饱和聚酯树脂的方法
- 专利标题: Process of curing unsaturated polyester resins using acetylenic diperesters
- 专利标题(中): 使用乙酰基DIPERESTER固化不饱和聚酯树脂的方法
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申请号: US3553291D申请日: 1968-07-15
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公开(公告)号: US3553291A公开(公告)日: 1971-01-05
- 发明人: FRIEDMAN RONALD L , LEWIS ROGER N
- 申请人: ARGUS CHEM
- 专利权人: Argus Chem
- 当前专利权人: Argus Chem
- 优先权: US51135465 1965-12-03; US77087968 1968-07-15
- 主分类号: C07C409/04
- IPC分类号: C07C409/04 ; C08F283/01 ; C08F21/00 ; C08G17/12
摘要:
ALIPHATIC DIPERESTERS OF ALKYNE DIOLS HAVING THE FORMULA:
R5-CO-O-O-C(-R1)(-R2)-(C*C)M-(CH2)P-(C*C)N-C(-R3)(-R4)-O-
O-CO-R6
WHERE R1, R2, R3 AND R4 ARE LOWER HYDROCARBON GROUPS, M AND N ARE 0 OR 1 WITH THE PROVISO THAT THEIR SUM IS ALWAYS AT LEAST ONE, P IS A POSITIVE INTEGER, AND R5 AND R6 ARE THE SAME OR DIFFERENT ALIPHATIC GROUPS OF FROM 1 TO 20 CARBON ATOMS ARE USEFUL AS CATALYSTS FOR THE FREE RADICAL INITIATED POLYMERIZATION OF POLYESTERS. USE OF THESE DIPERESTERS AS CATALYSTS ELIMINATE VARIOUS DISTORIONS IN THE STRUCTURE OF THE FINISHED MOLDED RESIN PRODUCT.
R5-CO-O-O-C(-R1)(-R2)-(C*C)M-(CH2)P-(C*C)N-C(-R3)(-R4)-O-
O-CO-R6
WHERE R1, R2, R3 AND R4 ARE LOWER HYDROCARBON GROUPS, M AND N ARE 0 OR 1 WITH THE PROVISO THAT THEIR SUM IS ALWAYS AT LEAST ONE, P IS A POSITIVE INTEGER, AND R5 AND R6 ARE THE SAME OR DIFFERENT ALIPHATIC GROUPS OF FROM 1 TO 20 CARBON ATOMS ARE USEFUL AS CATALYSTS FOR THE FREE RADICAL INITIATED POLYMERIZATION OF POLYESTERS. USE OF THESE DIPERESTERS AS CATALYSTS ELIMINATE VARIOUS DISTORIONS IN THE STRUCTURE OF THE FINISHED MOLDED RESIN PRODUCT.
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