摘要:
This invention relates to a process for molding a thermosetting resinous composition, which comprises heating a liquid composition comprising an unsaturated alkyd resin, a vinyl chloride resin, a vinyl monomer and/or a reactive plasticizer, and a polymerization initiator at a temperature ranging from 80* to 160*C. to such an extent that the composition is not completely cured, cooling the composition to obtain a non-tacky partially-cured composition of a suitable form, and heating said partially-cured composition at a temperature ranging from 120* to 180*C. to complete the curing.
摘要:
1. A THERMOSETTING MOULDING COMPOSITION WHICH IS FREEFLOWING AT ROOM TEMPERATURE, SAID MOULDING COMPOSITION COMPRISING (1) A POLYESTER OF AN A,B-ETHYLENICALLY UNSATURATED DICARRBOXYLIC ACID AND A POLYHYDRIC ALKANOL AND (2) A COMPOUND OF THE FORMULA
X-(NH-CO-N(-R)-CO-C(-R'')=CH2)N
WHEREIN X IS AN ALIPHATIC, CYCLOALIIPHATIC OR AROMATIC RADICAL, N IS THE VALENCY OF X, R IS HYDROGEN, ALKYL OR ARYL AND R'' IS HYDROGEN OR METHYL.
摘要:
1. A STORAGE STABLE COPOLYMERIZABLE MIXTURE CONSISTING ESSENTIALLY OF A LIQUID UNSATURATED POLYESTER RESINSAID RESIN BEING OBTAINED BY THE ESTERIFICATION OF A COMPOUND SELECTED FROM THE GROUP CONSISTING OF AN ALPHA, BETA-ETHYLENIC DICARBOXYLIC ACID AND THE ANHYDRIDE THEREOF WITH A POLYHYDRIC ALCOHOL, A REACTIVE MONOMERIC SUBSTANCE HAVING A CH2=C
摘要:
SUCH AS 2,2-DI(T-BUTYLPEROXY)-4-METHYLPENTANE AND 4,4DI(T-BUTYLPEROXY)HEPTANE.
R3-C(-R2)(-R4)-C(-R5)(-R6)-C(-O-O-R1)2-R
IMPROVEMENTS IN THE POLYMERIZATION OF ETHYLENICALLY UNSATURATED MONOMERS, THE CURING OF UNSATURATED POLYESTER RESIN COMPOSITIONS, AND THE CURING (PREFERABLY CURING AND FOAMING) OF ELASTOMER COMPOSITIONS ARE ACHIEVED BY THE USE OF CERTAIN B-SUBSTITUTED DIPEROXYKETALS OF THE FORMULA
摘要:
New polymeric thermoplastic compounds having favorable properties are obtained by reacting substantially linear polycarbonates containing polymerizable unsaturated groups dissolved in inert solvents or dispersed in nonsolvents with radical-polymerizable olefins or derivatives thereof or mixtures thereof under polymerization conditions.
摘要:
LIQUID COMPOSITIONS WHICH ARE FREE OF UNREACTIVE SOLVENT AND CAPABLE OF BEING POLYMERIZED UPON ADDITION OF FREE-RADICAL POLYMERIZATION CATALYST (E.G., ORGANIC PEROXIDE) INTO SOLID THERMOSET RESINS, ARE MADE BY FORMING UNSATURATED POLYESTERS HAVING AN AVERAGE MOLECULAR WEIGHT OF ABOUT 1,000 T 25,000 AND AN AVERAGE OF 6 TO 110 DOUBLE BOND UNSATURATED, AT LEAST 50% OF WHICH ARE MALEATE UNSATURATIONS, BY POLYMERIZATION IN THE PRESENCE OF A DOUBLE METAL CYANIDE COMPLEX CATALYST OF UNSATURATED DICARBOXYLIC ACID ANHYDRIDES AND ALKYLENE OXIDES IN THE PRESENT OF MONOMERIC UNSATURATED ESTERS THAT DO NOT UNDERGO APPRECIABLE COPOLYMERIZATION AT TEMPERATURES OF 100*C. OR BELOW, THAT ARE COMPATIBLE WITH THE UNSATURATED POLYESTERS AND THAT ARE CAPABLE OF COPOLYMERIZATION WITH THE POLYESTERS. THE MONOMERIC UNSATURATED ESTER ACTS AS A SOLVENT FOR THE POLYESTER DURING ITS FORMATION AND IN THE LIQUID COMPOSITION AND SERVES TO CROSS-LINKED POLYESTER WHEN THE LIQUID COMPOSITION IS POLYMERIZED UNDER THE INFLUENCE OF THE FREERADICAL POLYMERIZATION CATALYST.
摘要:
WHERE N RANGES FROM 3 TO 8, RESINS BEING USED AS A BASIS FOR PREPARING VARIOUS LAMINATED PLASTICS ADHESIVES, VARNISHES AND COMPOUNDS.
CH2=CHOOC(CH2)NCOOCH=CH2
A METHOD OF PRODUCING UNSATURATED POLYESTER RESINS THAT CONTAIN TERMINAL VINYL GROUPS IN THE POLYMER CHAIN, THAT SET WITHOUT ADDITIONAL INTRODUCTION OF A CROSS-LINKING MONOMER, WITH THE FORMATION OF POLYMERS FEATURING HIGH THERMOSTABILITY AND MECHANICAL STRENGTH; THE METHOD RESIDING IN CONDENSING POLYHYDRIC ALCOHOLS WITH UNSATURATED ACIDS OR ANHYDRIDES THEREOF, OR WITH MIXTURES OF SATURATED AND UNSATURATED ACIDS OR ANHYDRIDES THEREOF, WITH THE INTRODUCTION DIRECTLY AT THE POLYCONDENSING STAGE OF AT LEAST ONE DIVINYL ESTER OF ALIPHATIC DICARBOXYLIC ACIDS OF THE FORMULA
WHERE R1, R2, R3 AND R4 ARE LOWER HYDROCARBON GROUPS, M AND N ARE 0 OR 1 WITH THE PROVISO THAT THEIR SUM IS ALWAYS AT LEAST ONE, P IS A POSITIVE INTEGER, AND R5 AND R6 ARE THE SAME OR DIFFERENT ALIPHATIC GROUPS OF FROM 1 TO 20 CARBON ATOMS ARE USEFUL AS CATALYSTS FOR THE FREE RADICAL INITIATED POLYMERIZATION OF POLYESTERS. USE OF THESE DIPERESTERS AS CATALYSTS ELIMINATE VARIOUS DISTORIONS IN THE STRUCTURE OF THE FINISHED MOLDED RESIN PRODUCT.