Process for molding thermosetting resinous compositions
    1.
    发明授权
    Process for molding thermosetting resinous compositions 失效
    用于模塑热固性树脂组合物的方法

    公开(公告)号:US3856885A

    公开(公告)日:1974-12-24

    申请号:US30099872

    申请日:1972-10-26

    发明人: FURUYA A ISHIMARU Y

    IPC分类号: C08G63/52 C08L67/06 C08F21/00

    CPC分类号: C08G63/52 C08L67/06 C08L27/04

    摘要: This invention relates to a process for molding a thermosetting resinous composition, which comprises heating a liquid composition comprising an unsaturated alkyd resin, a vinyl chloride resin, a vinyl monomer and/or a reactive plasticizer, and a polymerization initiator at a temperature ranging from 80* to 160*C. to such an extent that the composition is not completely cured, cooling the composition to obtain a non-tacky partially-cured composition of a suitable form, and heating said partially-cured composition at a temperature ranging from 120* to 180*C. to complete the curing.

    摘要翻译: 本发明涉及一种热固性树脂组合物成型方法,该方法包括在80℃的温度范围内加热包含不饱和醇酸树脂,氯乙烯树脂,乙烯基单体和/或反应性增塑剂的液体组合物和聚合引发剂 DEG至160℃至组合物未完全固化的程度,冷却组合物以获得合适形式的非粘性部分固化组合物,并在120℃的温度范围加热所述部分固化的组合物 至180℃以完成固化。

    Unsaturated polyester resin formation in unsaturated ester monomer as solvent
    6.
    发明授权
    Unsaturated polyester resin formation in unsaturated ester monomer as solvent 失效
    不饱和聚酯树脂在不饱和酯单体中的形成作为溶剂

    公开(公告)号:US3662024A

    公开(公告)日:1972-05-09

    申请号:US3662024D

    申请日:1970-11-24

    发明人: GREENE CHARLES E

    CPC分类号: C08F283/01 C08G63/58

    摘要: LIQUID COMPOSITIONS WHICH ARE FREE OF UNREACTIVE SOLVENT AND CAPABLE OF BEING POLYMERIZED UPON ADDITION OF FREE-RADICAL POLYMERIZATION CATALYST (E.G., ORGANIC PEROXIDE) INTO SOLID THERMOSET RESINS, ARE MADE BY FORMING UNSATURATED POLYESTERS HAVING AN AVERAGE MOLECULAR WEIGHT OF ABOUT 1,000 T 25,000 AND AN AVERAGE OF 6 TO 110 DOUBLE BOND UNSATURATED, AT LEAST 50% OF WHICH ARE MALEATE UNSATURATIONS, BY POLYMERIZATION IN THE PRESENCE OF A DOUBLE METAL CYANIDE COMPLEX CATALYST OF UNSATURATED DICARBOXYLIC ACID ANHYDRIDES AND ALKYLENE OXIDES IN THE PRESENT OF MONOMERIC UNSATURATED ESTERS THAT DO NOT UNDERGO APPRECIABLE COPOLYMERIZATION AT TEMPERATURES OF 100*C. OR BELOW, THAT ARE COMPATIBLE WITH THE UNSATURATED POLYESTERS AND THAT ARE CAPABLE OF COPOLYMERIZATION WITH THE POLYESTERS. THE MONOMERIC UNSATURATED ESTER ACTS AS A SOLVENT FOR THE POLYESTER DURING ITS FORMATION AND IN THE LIQUID COMPOSITION AND SERVES TO CROSS-LINKED POLYESTER WHEN THE LIQUID COMPOSITION IS POLYMERIZED UNDER THE INFLUENCE OF THE FREERADICAL POLYMERIZATION CATALYST.