发明授权
- 专利标题: Elastomeric materials and process therefor
- 专利标题(中): 弹性材料及其过程
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申请号: US65570767申请日: 1967-06-14
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公开(公告)号: US3673280A公开(公告)日: 1972-06-27
- 发明人: MINTON ROBERT G , MELAMED SIDNEY
- 申请人: ROHM & HAAS
- 专利权人: Rohm and Haas Company
- 当前专利权人: Rohm and Haas Company
- 优先权: US65570767 1967-06-14
- 主分类号: C08F2/22
- IPC分类号: C08F2/22 ; C08F265/04 ; C08F15/00
摘要:
Elastomeric materials and methods of producing them comprising: A. About 50-90 percent by weight of a base elastomeric composition as a ''''backbone'''' or main component formed by copolymerizing a mixture comprising 1. ABOUT 75-99.9 PERCENT BY WEIGHT OF THE BASE COMPOSITION OF AT LEAST ONE MONOMER POLYMERIZABLE TO GIVE A RUBBERY POLYMER AND SELECTED FROM THE GROUP CONSISTING OF ALKYL (C2-C8) acrylates, and mixtures thereof with each other and with up to an equal weight amount of ethylene, propylene, or isobutylene; and 2. AT LEAST ABOUT 0.1 PERCENT BY WEIGHT OF THE BASE COMPOSITION OF AT LEAST ONE ETHYLENICALLY UNSATURATED MONOMER COPOLYMERIZABLE WITH (A)(1) and containing at least one radical effective to crosslink said base composition by a reaction which is activated separately from the polymerization reaction; and B. About 50-10 percent by weight of a reinforcing material for the base composition and dispersed throughout the base composition consisting of a polymer of 1. AT LEAST ONE HALOGEN MONOMER SELECTED FROM THE GROUP CONSISTING OF VINYLIDENE CHLORIDE, VINYLIDENE FLUORIDE, VINYLIDENE FLUOROCHLORIDE, VINYL CHLORIDE AND VINYL FLUORIDE; AND 2. UP TO ABOUT 6 PERCENT BY WEIGHT OF THE MIXTURE OF AT LEAST ONE Alpha , Beta -MONOETHYLENICALLY UNSATURATED MONOMER COPOLYMERIZABLE WITH (B)(1). The backbone is crosslinked by virtue of the reaction of the radicals in monomer (A)(2) to make the backbone solvent insoluble. The backbone may optionally contain a diluent and/or a hardener, the latter being a monomer effective to raise the glass transition temperature of the copolymer. Preferably, the elastomers are spun into fibers or extruded into films. This application is a continuation-in-part of Ser. No. 372,476 filed June 4, 1964.
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