发明授权
- 专利标题: Copolymers of vinyl chloride and lower olefins
- 专利标题(中): 氯乙烯和低烯烃的共聚物
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申请号: US3683051D申请日: 1969-02-25
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公开(公告)号: US3683051A公开(公告)日: 1972-08-08
- 发明人: CHATELAIN JEAN
- 申请人: PECHINEY SAINT GOBAIN
- 专利权人: Pechiney Saint Gobain
- 当前专利权人: Pechiney Saint Gobain
- 优先权: FR142369 1968-03-05
- 主分类号: C08F259/04
- IPC分类号: C08F259/04 ; C08F15/00
摘要:
Vinyl chloride is first polymerized in mass with high turbulent agitation to from 7 to 15 percent completion forming suspended polymer seeds in the liquid monomer, the suspension is added to a mixture of liquid vinyl chloride and low molecular weight olefin, and polymerization in mass is continued to completion, producing grains having a seed of the homopolymer of vinyl chloride surrounded by the copolymer. The first stage with high turbulence is carried out under warm conditions of usually about 50* to 60* C. and the second stage is carried out at from about -40* to +80* C. with mild agitation. The product is concentrated in a narrow range of particle sizes, e.g. 80 percent between 100 and 250 microns.
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