发明授权
US3812192A Process for the manufacture of polythiobisphenols 失效
制备多羟基苯酚的方法

Process for the manufacture of polythiobisphenols
摘要:
A PHENOL WHICH IS UNSUBSTITUTED AT THE POSITION PARA TO THE HYDROXY GROUP OR UNSUBSTITUTED AT AT LEAST ONE OF THE POSITIONS ORTHO TO THE HYDROXY GROUP IS DISSOLVED IN A SOLVENT, IN THE ABSENCE OF HYDROGEN SULFIDE AND CATALYSTS, AND WHILE COOLING TO A TEMPERATURE BELOW 30* C. IS REACTED WITH DISULFUR DICHLORIDE. THE SOLVENT IS AN ACID AMIDE WHOSE NITROGEN ATOMS ARE COMPLETELY ALKYLATED. POLYTHIOBISPHENOLS ARE OBTAINED IN HIGH YIELD.
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