摘要:
A PROCESS FOR THE MANUFACTURE OF A LINEAR HIGH POLYMERIC POLY-N-ALKYLHYDRAZIDE WHEREIN A HYDRAZINE IS CONDENSED IN CHLOROSULPHONIC ACID AT AN ELEVATED TEMPERATURE WITH AN AROMATIC DICARBOXYLIC ACID DIESTER. THE HYDRAZINE OPTIONALLY HAS A LOWER ALKYL SUBSTITUTION AT ONE OF ITS HYDROGEN ATOMS.
摘要:
A PHENOL WHICH IS UNSUBSTITUTED AT THE POSITION PARA TO THE HYDROXY GROUP OR UNSUBSTITUTED AT AT LEAST ONE OF THE POSITIONS ORTHO TO THE HYDROXY GROUP IS DISSOLVED IN A SOLVENT, IN THE ABSENCE OF HYDROGEN SULFIDE AND CATALYSTS, AND WHILE COOLING TO A TEMPERATURE BELOW 30* C. IS REACTED WITH DISULFUR DICHLORIDE. THE SOLVENT IS AN ACID AMIDE WHOSE NITROGEN ATOMS ARE COMPLETELY ALKYLATED. POLYTHIOBISPHENOLS ARE OBTAINED IN HIGH YIELD.
摘要:
POLYMERIC COMPOUNDS OF THE FORMULA -X1-AR1-(Y1-AR1)N1-X2-(AR2-Y2)N2-AR2WHEREIN X1 AND X2 ARE INDEPENDENTLY EITHER OXYGEN OR SULPHUR, AR1 AND AR2 ARE THE SAME OR DIFFERENT AROMATIC RADICALS,N1 AND N2 ARE INDEPENDENTLY OF ONE ANOTHER THE NUMBERS 0-2, AND Y1 AND Y2 ARE INDEPENDENTLY OF ONE ANOTHER A SIMPLE BOND OR A DIVALENT RADICALS, PARTICULARLY ONE OF THE SERIES -O-, -CONH-, -S-, -SO2-, -CO-, -CH2-, -C(CH3)2-, -N=N-, IN WHICH EACH AR IS ATTACHED TO ADJCENT RING MEMBER BY TWO CARBON ATOMS WHICH ARE NOT ADJACENT ONE ANOTHER, AND IS CHARACTERIZED IN THAT AT LEAST ONE COMPOUND OF THE FORMULA: H-X1-AR1-(Y1-AR1)N1-X2-H IS TREATED WITH AT LEAST ONE COMPOUND OF THE FORMULLA: HAL-(AR2-Y2)N2-AR2-HAL IN WHICH HAL REPRESENTS HALOGEN, PARTICULARLY CHLORINE OR BROMINE, AND X1, X2 AND AR1, AR2, N1, N2, Y1 AND Y2 HAVE THE SIGNIFICANCE STATED IN FORMULA I, IN THE PRESENCE OF THE QUANTITY NECESSARY FOR NEUTRALIZATION OF HYDROGEN-HALIDE IN PARTICULAR 1-20% BY WEIGHT EXCESS CALCULATED ON THE STARTING MATERIAL OF AN INORGANIC OR ORGANIC BASE AS ACID ACCEPTOR, IN A SOLVENT OF THE FORMULA: A-N
摘要:
PROCESS FOR THE MANUFACTURE OF LINEAR AROMATIC POLY1,3,4-OXADIAZOLES BY REACTING IN CHLOROSULPHONIC ACID AN INORGANIC HYDRAZINE SALT AND AN AROMATIC DCARBOXYLIC ACID.
摘要:
AN IMPROVED PROCESS FOR THE PREPARATION OF SHAPED ARTICLES WHEREIN A POLYAMIDE IS FORMED BY THE POLYCONDENSATION OF A CORRESPONDING DIAMINE AND A CORRESPONDING ACID CHLORIDE IN A SOLVENT. THE SOLVENT HAVING THE FORMULA:
R-N WHEREIN R IS AN ALKYL RADICAL HAVING 1-4 CARBON ATOMS AND N IS A WHOLE NUMBER BETWEEN 5 AND 7.