发明授权
- 专利标题: Polymers of conjugated diene hydrocarbons and method of preparation
- 专利标题(中): 共轭二烯烃聚合物及其制备方法
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申请号: US45837274申请日: 1974-04-05
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公开(公告)号: US3872071A公开(公告)日: 1975-03-18
- 发明人: HENDERSON JAMES NEIL , SHAHEEN FRANK G
- 申请人: GOODYEAR TIRE & RUBBER
- 专利权人: Goodyear Tire & Rubber
- 当前专利权人: Goodyear Tire & Rubber
- 优先权: US45837274 1974-04-05; US27830772 1972-08-07; US11372671 1971-02-08; US77677068 1968-11-18
- 主分类号: C08F36/04
- IPC分类号: C08F36/04 ; C08D1/14 ; C08D5/02 ; C08D5/04
摘要:
Polymers of conjugated diene hydrocarbons and a method for their preparation which comprises (A) polymerizing the conjugated diene to form a polymer having substantially a trans-1,4 structure in the presence of a catalyst prepared by mixing a vanadium compound selected from vanadium trichloride and the product of vanadium tetrachloride and titanium tetrachloride with at least one organo aluminum compound and with up to 3 moles of a titanium compound per mole of vanadium compound where the titanium compound is selected from the group consisting of titanium triacetylacetonate and the compounds having the formula Ti(OR'')4 and (B) mixing oxygen with the polymerized diene hydrocarbon and catalyst to reduce the molecular weight of the polymer.