发明授权
- 专利标题: Pre-emulsification-delayed initiation suspension pearl polymerization process
- 专利标题(中): 预乳化延迟引发悬浮珠光聚合方法
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申请号: US36083573申请日: 1973-05-16
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公开(公告)号: US3882195A公开(公告)日: 1975-05-06
- 发明人: DANIELS WILEY E , HOLLAND DEWEY G , MANTELL GERALD J
- 申请人: AIR PROD & CHEM
- 专利权人: Air Prod & Chem
- 当前专利权人: Air Prod & Chem
- 优先权: US36083573 1973-05-16
- 主分类号: C08F14/00
- IPC分类号: C08F14/00 ; C08F2/00 ; C08F2/18 ; C08F2/24 ; C08F14/06 ; C08F291/00 ; C08F15/00 ; C08F19/00
摘要:
A process for preparing vinyl chloride based polymers by suspension polymerization provides granular products characterized by improved uniformity of particle size, high porosity and rapid fushion rates. Pre-emulsification of vinyl chloride in the presence of a polyvalent metal ion, a surface active agent and a ''''seed'''' polymer, subsequently polymerized by the after-addition of initiator offers a high degree of control over physical properties of the resulting polymer that are also consistently reproducible. By addition of surfactants during the course of polymerization stability is improved. The combination of pre-emulsification, delayed initiation and post addition of surfactant substantially eliminates reactor wall fouling and crust formation.
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