发明授权
- 专利标题: Process for the production of water-adsorbing cellulose ethers
- 专利标题(中): 生产吸水纤维素醚的方法
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申请号: US683967申请日: 1976-05-06
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公开(公告)号: US4066828A公开(公告)日: 1978-01-03
- 发明人: Arno Holst , Helmut Lask , Michael Kostrzewa
- 申请人: Arno Holst , Helmut Lask , Michael Kostrzewa
- 申请人地址: DT
- 专利权人: Hoechst Aktiengesellschaft
- 当前专利权人: Hoechst Aktiengesellschaft
- 当前专利权人地址: DT
- 优先权: DT2520337 19750507
- 主分类号: A61F13/472
- IPC分类号: A61F13/472 ; A61F13/15 ; A61F13/53 ; A61L15/28 ; A61L15/60 ; C08B11/187 ; C08B15/00 ; C08B15/10 ; C08B11/00 ; C08B11/193 ; C08B11/20
摘要:
This invention relates to an improvement in the process for the production of water-adsorbing, but at least partially water-insoluble, cellulose ethers in which cellulose is alkalized in a liquid reaction medium and etherified in a manner such that by etherification only an at least largely water-soluble carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, hydroxyethyl cellulose or methyl hydroxyethyl cellulose is produced, and in which the cellulose is reacted in an alkaline reaction medium before, during, or after the etherification with a cross-linking agent which is polyfunctional towards cellulose and selected from the group consisting of acrylamido methylene chloroacetamide, dichloroacetic acid, phosphorous oxychloride, or a compound in which at least two groups functional towards cellulose are ##STR1## the improvement comprising effecting alkalization, etherification, and cross-linking in a liquid reaction medium other than isopropyl alcohol.
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