发明授权
- 专利标题: Process for the manufacture of indigoid dyes
- 专利标题(中): 靛蓝染料的制造方法
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申请号: US751223申请日: 1976-12-16
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公开(公告)号: US4151170A公开(公告)日: 1979-04-24
- 发明人: Jacques Gosteli
- 申请人: Jacques Gosteli
- 申请人地址: CHX Basel
- 专利权人: Ciba-Geigy AG
- 当前专利权人: Ciba-Geigy AG
- 当前专利权人地址: CHX Basel
- 优先权: CHX16782/75 19751224
- 主分类号: C09B7/00
- IPC分类号: C09B7/00 ; C07C67/00 ; C07C201/00 ; C07C205/45 ; C09B7/02 ; D06P1/28 ; D06P3/60
摘要:
A process for the manufacture of indigoid dyes, wherein a functional derivative of the anthranilic acid of the general formula I ##STR1## in which A completes a mono- or polynuclear, substituted or unsubstituted aromatic ring,X represents a hydrogen atom or a protective group for the free amino group which can form an anhydro derivative with the carboxyl group in the ortho-position,Is reacted with nitromethane in the presence of a base or with a salt of nitroacetic acid to give the .omega.-nitro-o-amino-acetophenone derivative of the general formula II ##STR2## in which A and X are as defined in formula I, and this intermediate is condensed by heating with acids to give the indigo compound of the general formula III ##STR3## in which A is as defined in formula I.
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