发明授权
US4162947A Acid zinc plating baths and methods for electrodepositing bright zinc deposits 失效
酸性锌电镀浴和电沉积亮锌沉积物的方法

  • 专利标题: Acid zinc plating baths and methods for electrodepositing bright zinc deposits
  • 专利标题(中): 酸性锌电镀浴和电沉积亮锌沉积物的方法
  • 申请号: US908567
    申请日: 1978-05-22
  • 公开(公告)号: US4162947A
    公开(公告)日: 1979-07-31
  • 发明人: Valerie M. Canaris
  • 申请人: Valerie M. Canaris
  • 申请人地址: OH Cleveland
  • 专利权人: R. O. Hull & Company, Inc.
  • 当前专利权人: R. O. Hull & Company, Inc.
  • 当前专利权人地址: OH Cleveland
  • 主分类号: C25D3/22
  • IPC分类号: C25D3/22
Acid zinc plating baths and methods for electrodepositing bright zinc
deposits
摘要:
An aqueous acidic plating bath for the electrodeposition of a bright zinc deposit on a substrate is disclosed and comprises zinc ions, ammonium ions and at least one aromatic sulfonic acid or salt having the general formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently hydrogen or lower alkyl groups,X is hydrogen, ammonia or any metal with the proviso that the metal sulfonate is soluble in the bath, andA is a saturated, unsaturated or aromatic ring.Additionally, the plating baths of the invention may contain aromatic carbonyl-containing compounds and particularly aromatic aldehydes containing at least one halogen substituent. Polyoxyalkylated naphthols and polyalkylene glycol ethers as well as poly(alkyleneimines) also are contemplated as being useful in the plating baths of the invention. Methods for depositing a bright zinc coating over a wide range of current densities, and additive compositions for preparing plating baths useful in these methods also are described.
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