发明授权
US4205157A Method for production of high molecular weight polyester with low catalyst level and low carboxyl content 失效
低催化剂水平和低羧基含量的高分子量聚酯的生产方法

Method for production of high molecular weight polyester with low
catalyst level and low carboxyl content
摘要:
A high molecular weight polyester is disclosed, having a low carboxyl content, and utilizing a low catalyst level, produced by a two-stage process; a melt process until the intrinsic viscosity of the prepolymer reaches about between 0.15 and 0.45 dl/g, and a solid state polymerization in a fluidized bed until the intrinsic viscosity of the polycondensed polymer reaches at least 0.60 dl/g. The melt process employs addition of excess initial glycol, delayed addition of excess glycol, and delayed addition of catalyst, in any combination, to achieve a low carboxyl content polyester prepolymer capable of use in the fluidized bed solid state polymerization. This prepolymer with a minimal carboxyl content achieves a maximum solid state polymerization rate in a fluidized bed. This prepolymer also permits the use of a very low catalyst level to achieve high product purity and still maintains economically satisfactory polymerization rate. Stability and color clarity of the polycondensed product is obtained by this method.
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