发明授权
- 专利标题: Method for production of high molecular weight polyester with low catalyst level and low carboxyl content
- 专利标题(中): 低催化剂水平和低羧基含量的高分子量聚酯的生产方法
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申请号: US25697申请日: 1979-04-02
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公开(公告)号: US4205157A公开(公告)日: 1980-05-27
- 发明人: Ben Duh
- 申请人: Ben Duh
- 申请人地址: OH Akron
- 专利权人: The Goodyear Tire & Rubber Company
- 当前专利权人: The Goodyear Tire & Rubber Company
- 当前专利权人地址: OH Akron
- 主分类号: C08G63/00
- IPC分类号: C08G63/00 ; C08G63/18 ; C08G63/78 ; C08G63/80 ; C08G63/36
摘要:
A high molecular weight polyester is disclosed, having a low carboxyl content, and utilizing a low catalyst level, produced by a two-stage process; a melt process until the intrinsic viscosity of the prepolymer reaches about between 0.15 and 0.45 dl/g, and a solid state polymerization in a fluidized bed until the intrinsic viscosity of the polycondensed polymer reaches at least 0.60 dl/g. The melt process employs addition of excess initial glycol, delayed addition of excess glycol, and delayed addition of catalyst, in any combination, to achieve a low carboxyl content polyester prepolymer capable of use in the fluidized bed solid state polymerization. This prepolymer with a minimal carboxyl content achieves a maximum solid state polymerization rate in a fluidized bed. This prepolymer also permits the use of a very low catalyst level to achieve high product purity and still maintains economically satisfactory polymerization rate. Stability and color clarity of the polycondensed product is obtained by this method.
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