发明授权
US4315029A Racemic modification consisting of specific isomers of
.alpha.-cyano-3-phenoxybenzyl cis- or
trans-2,2-dimethyl-3-(2,2,2-trichloroethyl)cyclopropanecarboxylate,
production thereof and pesticidal compositions containing the same
失效
外消旋改性由α-氰基-3-苯氧基苄基顺式或反式-2,2-二甲基-3-(2,2,2-三氯乙基)环丙烷羧酸酯的特殊异构体组成,其生产和含有它们的杀虫组合物
- 专利标题: Racemic modification consisting of specific isomers of .alpha.-cyano-3-phenoxybenzyl cis- or trans-2,2-dimethyl-3-(2,2,2-trichloroethyl)cyclopropanecarboxylate, production thereof and pesticidal compositions containing the same
- 专利标题(中): 外消旋改性由α-氰基-3-苯氧基苄基顺式或反式-2,2-二甲基-3-(2,2,2-三氯乙基)环丙烷羧酸酯的特殊异构体组成,其生产和含有它们的杀虫组合物
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申请号: US128717申请日: 1980-03-10
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公开(公告)号: US4315029A公开(公告)日: 1982-02-09
- 发明人: Fumio Mori , Yoshiaki Omura , Yoshiji Fujita , Takashi Nishida , Takeo Hosogai , Fumio Wada , Sukeji Aihara , Yoshin Tamai , Kazuo Itoi
- 申请人: Fumio Mori , Yoshiaki Omura , Yoshiji Fujita , Takashi Nishida , Takeo Hosogai , Fumio Wada , Sukeji Aihara , Yoshin Tamai , Kazuo Itoi
- 申请人地址: JPX Kurashiki
- 专利权人: Kuraray Co., Ltd.
- 当前专利权人: Kuraray Co., Ltd.
- 当前专利权人地址: JPX Kurashiki
- 优先权: JPX54-27282 19790308; JPX54-51677 19790425
- 主分类号: A01N53/00
- IPC分类号: A01N53/00 ; A01N53/08 ; C07C121/75
摘要:
Racemic modifications each consisting of specific isomers of .alpha.-cyano-3-phenoxybenzyl cis- or trans-2,2-dimethyl-3-(2,2,2-trichloroethyl)cyclopropanecarboxylate with the absolute configurations [.alpha.S, 1R] an [.alpha.R, 1S] with respect to the asymmetric carbon atoms in the alcohol and acid moieties, a method of producing the same and pesticidal compositions containing the same as active ingredient are provided. .alpha.-Cyano-3-phenoxybenzyl cis- or trans-2,2-dimethyl-3-(2,2,2-trichloroethyl)cyclopropanecarboxylate has higher pesticidal activities than those pesticides that are in general use and consequently selective production of the above specific racemic modification as defined by the combinations of the absolute configuration with respect to the asymmetric carbon atom at the position in the alcohol moiety and the absolute configuration with respect to the asymmetric carbon atom in the acid moiety provides compounds having still higher pesticidal activities.
公开/授权文献
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