发明授权
- 专利标题: Catalytic alkylation of hydrocarbons
- 专利标题(中): 碳氢化合物的催化烷基化
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申请号: US124994申请日: 1980-02-26
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公开(公告)号: US4317795A公开(公告)日: 1982-03-02
- 发明人: Donald J. Makovec , Donald M. Haskell
- 申请人: Donald J. Makovec , Donald M. Haskell
- 申请人地址: OK Bartlesville
- 专利权人: Phillips Petroleum Company
- 当前专利权人: Phillips Petroleum Company
- 当前专利权人地址: OK Bartlesville
- 主分类号: B01J19/00
- IPC分类号: B01J19/00 ; C07C2/54 ; C07C2/62 ; G01N21/00 ; G05D7/00
摘要:
A continuous process for the alkylation of an alkylatable hydrocarbon with an alkylating agent in the presence of an acid-type catalyst, including; contacting an alkylatable hydrocarbon with an alkylating agent in the presence of an acid-type catalyst at a temperature and pressure and for a time sufficient to alkylate the alkylatable hydrocarbon; separating the reaction effluent stream into an alkylate product phase and a catalyst phase containing catalyst-soluble oil; cooling the catalyst phase to a temperature essentially equal to the alkylation reaction temperature; recycling the cooled catalyst phase to the alkylation reaction; contacting a diolefinic hydrocarbon with an acid-type catalyst at a temperature and pressure sufficient to form additional catalyst-soluble oil and combining the additional catalyst-soluble oil with the circulating catalyst phase. In accordance with another aspect of the invention, a quantity selected from the amount of catalyst-soluble oil, water and/or the total of the amount of catalyst-soluble oil and water in the catalyst phase is controlled, within specific limits. A start-up procedure and apparatus for carrying out the process are also included.
公开/授权文献
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