发明授权
- 专利标题: High-molecular-weight novolak types substituted phenolic resins and process for preparation thereof
- 专利标题(中): 高分子量酚醛清漆型取代酚醛树脂及其制备方法
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申请号: US221333申请日: 1980-12-29
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公开(公告)号: US4345054A公开(公告)日: 1982-08-17
- 发明人: Nobuyuki Takeda , Tadao Iwata
- 申请人: Nobuyuki Takeda , Tadao Iwata
- 申请人地址: JPX Tokyo
- 专利权人: Mitsui Petrochemical Industries, Ltd.
- 当前专利权人: Mitsui Petrochemical Industries, Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX54-169140 19791227; JPX55-73754 19800603; JPX55-73755 19800603; JPX55-73756 19800603; JPX55-73757 19800603
- 主分类号: C08G8/04
- IPC分类号: C08G8/04 ; C08G8/24 ; C08L61/06 ; C08L63/00 ; C08L101/00 ; C08L61/14
摘要:
A high-molecular-weight novolak type substituted phenolic resin having a number average molecular weight of at least 1500 is prepared by reacting (A) (i) a phenol comprised mainly of a bifunctional phenol or (ii) a low-molecular-weight novolak type substituted phenolic resin derived from this phenol and an aldehyde with (B) a chain extender selected from the group consisting of (i) a dimethylolated product of a bifunctional or trifunctional phenol, (ii) a low-molecular-weight resol type substituted phenolic resin derived from a phenol comprised mainly of a bifunctional phenol and an aldehyde, (iii) an aldehyde, (iv) a ketone, (v) a diol and (vi) a dihalide in the presence of an acid catalyst, with the proviso that if the reactant (A) is the phenol (i), the chain extender is the resol type substituted phenolic resin (ii).The molecular weight of this novolak type substituted phenolic resin is much higher than the molecular weights of conventional novolak type phenolic resins, and if this phenolic resin is incorporated into various setting type resins, the heat resistance and mechanical properties of these resins can remarkably be improved.