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US4358404A Nondiffusible 6-arylazo-3-pyridinol 失效
不扩散的6-芳基偶氮-3-吡啶酚

Nondiffusible 6-arylazo-3-pyridinol
摘要:
Nondiffusible compounds are described having a releasable 6-arylazo-3-pyridinol magenta dye moiety or precursor thereof having the formula ##STR1## wherein: (a) R represents hydroxy or amino;(b) R.sup.1 represents hydrogen, a hydrolyzable moiety or CAR;(c) G represents carboxy; a hydrolyzable ester or a sulfamoyl group;(d) CAR represents a ballasted carrier moiety capable of releasing the diffusible 6-arylazo-3-pyridinol dye moiety or precursor thereof under alkaline conditions; and(e) n is 0, 1 or 2, with the proviso that when n is 0, then R.sup.1 is CAR; and wherein the phenyl ring is not substituted with a nitro group.These magenta dye-releasing compounds are used in photographic elements and diffusion transfer assemblages. The magenta dye moiety or precursor thereof is released as a function of development of a silver halide emulsion. The dye moiety then diffuses to an image-receiving layer where it forms a highly stable, metal-complexed dye transfer image.
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