发明授权
- 专利标题: Free-flowing sintering powders which have improved properties and are based on tetrafluoroethylene polymers, and a process for their manufacture
- 专利标题(中): 具有改进性能并基于四氟乙烯聚合物的自由流动的烧结粉末及其制造方法
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申请号: US214465申请日: 1980-12-08
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公开(公告)号: US4368296A公开(公告)日: 1983-01-11
- 发明人: Jurgen Kuhls , Robert Hartwimmer
- 申请人: Jurgen Kuhls , Robert Hartwimmer
- 申请人地址: DEX Frankfurt
- 专利权人: Hoechst Aktiengesellschaft
- 当前专利权人: Hoechst Aktiengesellschaft
- 当前专利权人地址: DEX Frankfurt
- 优先权: DEX2949908 19791212
- 主分类号: C08J3/12
- IPC分类号: C08J3/12 ; C08F14/00 ; C08F14/26 ; C08F214/26 ; C08F259/08 ; C08J3/16 ; C08L1/00 ; C08L27/00 ; C08L27/12 ; C08L27/18 ; C08F114/26
摘要:
Free-flowing sintering powders based on polymers containing at least 98.5% by weight of tetrafluoroethylene units can be prepared from colloidal polymer dispersions obtained in a customary manner by emulsion polymerization, stirring being carried out initially, optionally with the addition of an inorganic salt, until thickening, indicated by optical inhomogeneities, is achieved, an organic liquid which wets the polymer particles and is soluble in water to the extent of not more than 15% by weight then being added and stirring then being continued until granules are produced. The polymers preferably contain up to 1.5% by weight of polymerized units of at least one modifying, perfluorinated monomer. The free-flowing sintering powders have a high bulk density, an excellent flow time and further advantageous properties. They can be provided with customary fillers and are suitable for ram extrusion and for press-sintering processing to give sintered blocks and subsequently veneer-cut films.
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