发明授权
US4368296A Free-flowing sintering powders which have improved properties and are based on tetrafluoroethylene polymers, and a process for their manufacture 失效
具有改进性能并基于四氟乙烯聚合物的自由流动的烧结粉末及其制造方法

Free-flowing sintering powders which have improved properties and are
based on tetrafluoroethylene polymers, and a process for their
manufacture
摘要:
Free-flowing sintering powders based on polymers containing at least 98.5% by weight of tetrafluoroethylene units can be prepared from colloidal polymer dispersions obtained in a customary manner by emulsion polymerization, stirring being carried out initially, optionally with the addition of an inorganic salt, until thickening, indicated by optical inhomogeneities, is achieved, an organic liquid which wets the polymer particles and is soluble in water to the extent of not more than 15% by weight then being added and stirring then being continued until granules are produced. The polymers preferably contain up to 1.5% by weight of polymerized units of at least one modifying, perfluorinated monomer. The free-flowing sintering powders have a high bulk density, an excellent flow time and further advantageous properties. They can be provided with customary fillers and are suitable for ram extrusion and for press-sintering processing to give sintered blocks and subsequently veneer-cut films.
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