Invention Grant
US4483998A Simultaneous epoxide and carboxylic acid manufacture by co-oxidation in the presence of a copper-boron-silver catalyst 失效
在铜 - 硼 - 银催化剂存在下通过共氧化同时制备环氧化物和羧酸

Simultaneous epoxide and carboxylic acid manufacture by co-oxidation in
the presence of a copper-boron-silver catalyst
Abstract:
A process for simultaneously producing an epoxide and a carboxylic acid from an olefin and an aldehyde, respectively, by co-oxidation over a catalyst in the presence of oxygen is described. The catalyst is made by precipitating silver oxide in the presence of copper(II) oxide, copper(II) borate or a mixture thereof. These novel heterogeneous catalysts provide higher selectivities to the epoxide than those obtainable with commercial catalysts.
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