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1.发明授权Simultaneous epoxide and carboxylic acid manufacture by co-oxidation in the presence of a copper-boron-silver catalyst 失效在铜 - 硼 - 银催化剂存在下通过共氧化同时制备环氧化物和羧酸
公开(公告)号：US4483998A
公开(公告)日：1984-11-20
申请号：US484058
申请日：1983-04-11
IPC分类号： B01J23/89 , C07C51/235 , C07D301/06 , C07D303/04
CPC分类号： B01J23/8926 , C07C51/235 , C07D301/06 , C07D303/04
摘要： A process for simultaneously producing an epoxide and a carboxylic acid from an olefin and an aldehyde, respectively, by co-oxidation over a catalyst in the presence of oxygen is described. The catalyst is made by precipitating silver oxide in the presence of copper(II) oxide, copper(II) borate or a mixture thereof. These novel heterogeneous catalysts provide higher selectivities to the epoxide than those obtainable with commercial catalysts.
摘要翻译： 描述了通过在氧气存在下通过催化剂共氧化同时由烯烃和醛生成环氧化物和羧酸的方法。 催化剂通过在氧化铜（II），硼酸铜（II）或其混合物的存在下沉淀氧化银来制备。 这些新型的非均相催化剂提供了比用商业催化剂获得的更高的选择性。
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2.发明授权
公开(公告)号：US4803305A
公开(公告)日：1989-02-07
申请号：US125965
申请日：1987-11-27
IPC分类号： B01J31/04 , B01J31/22 , C07C29/50 , C07C45/33 , C07C409/04 , C07C179/025 , C07C31/12
CPC分类号： C07C409/04 , B01J31/2226 , C07C29/50 , C07C407/00 , C07C45/33 , B01J2231/70 , B01J2531/0216 , B01J2531/842 , Y02P20/52
摘要： The oxidation of isobutane in the presence of a novel, soluble catalyst of the formula Fe.sub.3 O(Pivalate).sub.6 (MeOH).sub.3 Cl is disclosed. Tertiary-Butyl alcohol, tertiary-butyl hydroperoxide, and acetone are produced. A significant increase in isobutane conversion is obtained without a large decrease in selectivity to tertiary-butyl alcohol and tertiary-butyl hydroperoxide using a small amount of catalyst. Tertiary-butyl alcohol is useful as a gasoline additive and tertiary-butyl hydroperoxide is used for the production of propylene oxide. Acetone has a variety of uses as well.
摘要翻译： 公开了在式Fe 3 O（新戊酸酯）6（MeOH）3Cl）的新型可溶性催化剂存在下异丁烷的氧化。 制备叔丁醇，叔丁基过氧化氢和丙酮。 在使用少量催化剂的叔丁醇和叔丁基过氧化氢的选择性没有大的降低的情况下，异丁烷转化率显着增加。 叔丁醇可用作汽油添加剂，叔丁基过氧化氢用于生产环氧丙烷。 丙酮也有各种用途。
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公开(公告)号：US4579978A
公开(公告)日：1986-04-01
申请号：US670102
申请日：1984-11-13
申请人： Jiang-Jen Lin , John R. Sanderson
发明人： Jiang-Jen Lin , John R. Sanderson
IPC分类号： C07C409/08 , C07D301/19 , C07C179/035
CPC分类号： C07D301/19 , C07C407/00 , C07C409/08
摘要： Substantially quantitative yields of bibenzyl hydroperoxide and bibenzyl dihydroperoxide can be obtained when oxygen is reacted with bibenzyl (1,2-diphenylethane) in the presence of a minor amount of sodium bicarbonate at a temperature within the range of about 100.degree. to about 160.degree. C. to provide an oxidation product wherein the bibenzyl is substantially selectively converted to the bibenzyl hydroperoxides. The bibenzyl hydroperoxides can be used as raw materials for the production of propylene oxide by reacting the bibenzyl hydroperoxides with propylene.
摘要翻译： 在少量碳酸氢钠存在下，在约100至约160℃的温度范围内，当与二苄基（1,2-二苯基乙烷）反应时，可以获得过氧化二苄苯基和联苄基二氢过氧化物的基本定量产率 以提供氧化产物，其中联苄基本上选择性地转化为联苯氢过氧化物。 苄基氢过氧化物可以用作通过使苄基氢过氧化物与丙烯反应生产环氧丙烷的原料。
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4.发明授权Process for oligomerizing olefins to prepare synthetic lubricant base stocks having improved properties 失效烯烃低聚制备具有改进性能的合成润滑剂基础油料的方法
公开(公告)号：US5146023A
公开(公告)日：1992-09-08
申请号：US516931
申请日：1990-04-30
IPC分类号： B01J21/16 , C07C2/08 , C07C2/14 , C07C2/22 , C07C9/22 , C10G50/02 , C10M107/10 , C10M107/12
CPC分类号： C10G50/02 , B01J21/16 , C07C2/08 , C07C2/14 , C07C2/22 , C07C9/22 , C10M107/10 , C10M107/12 , C07C2521/16 , C07C2527/128 , C07C2527/138 , C07C2527/25 , C10M2205/003 , C10M2205/0285 , C10M2205/043
摘要： A process is disclosed for preparing synthetic lubricant base stocks having improved properties. Synthetic lubricant base stocks may be prepared in good yield by oligomerizing linear olefins using certain acidic calcium montmorillonite clay catalysts. When a mixture of alpha and internal-olefins having up to 50 wt. % internal-olefin is used, and the oligomers prepared therefrom are hydrogenated, a synthetic lubricant base stock having a higher viscosity index and a lower pour point is prepared.
摘要翻译： 公开了一种制备具有改进性能的合成润滑剂基础油料的方法。 可以通过使用某些酸性钙蒙脱石粘土催化剂使线性烯烃低聚来制备合成润滑剂基础油料。 当α和内烯烃的混合物具有高达50wt。 使用％的内烯烃，并且由其制备的低聚物被氢化，制备具有较高粘度指数和较低倾点的合成润滑剂基础油料。
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5.发明授权Simultaneous epoxide and carboxylic acid manufacture by co-oxidation in the presence of a cobalt catalyst 失效在钴催化剂存在下通过共同氧化制备环氧化物和羧酸
公开(公告)号：US5068366A
公开(公告)日：1991-11-26
申请号：US563237
申请日：1990-08-06
IPC分类号： C07C51/235 , C07C51/25 , C07D301/06
CPC分类号： C07D301/06 , C07C51/235 , C07C51/252
摘要： A process for the preparation of isobutylene oxide and isobutyric acid from isobutylene and isobutyraldehyde, respectively, by a co-oxidation process conducted in the presence of oxygen and a cobalt salt catalyst at a temperature of about 20.degree. to about 180.degree. C. is disclosed.
摘要翻译： 公开了通过在约20℃至约180℃的温度下在氧和钴盐催化剂存在下进行的共氧化方法从异丁烯和异丁醛制备异丁烯和异丁酸的方法。 。
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公开(公告)号：US4980514A
公开(公告)日：1990-12-25
申请号：US444211
申请日：1989-12-01
CPC分类号： C07C49/175 , C07C45/29 , C07C45/30
摘要： Diketones useful as intermediates for reaction with carboxylic acids to provide surfactants and for reaction with amine adducts to provide fuel additives are prepared from polyoxyalkylene glycols having a molecular weight of about 200 to about 2,000 and having the formula: ##STR1## wherein R is hydrogen or methyl and wherein n is a positive number having a value of 1 to about 50,The polyoxyalkylene polyol is oxidized in the presence of a halogenated alkane solvent and a ruthenium catalyst with an alkali metal or alkaline earth metal hypochlorite at a temperature of about 10.degree. to about 50.degree. C. and a pressure of about 0 to 1,000 psig. over a period of about 10 to about 20 hours to provide the corresponding diketone having the formula: ##STR2## wherein R and n have the meaning given above.
摘要翻译： 可用作与羧酸反应以提供表面活性剂和与胺加合物反应以提供燃料添加剂的中间体的二酮由具有约200至约2,000的分子量的聚氧亚烷基二醇制备，具有下式：其中R 是氢或甲基，其中n为1至约50的正数。聚氧化烯多元醇在卤化烷烃溶剂和钌催化剂存在下，在碱金属或碱土金属次氯酸盐的存在下，在 约10℃至约50℃，压力为约0至1,000psig。 在约10至约20小时的时间内提供具有下式的相应二酮：其中R和n具有上述含义。
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7.发明授权
公开(公告)号：US4978799A
公开(公告)日：1990-12-18
申请号：US428812
申请日：1989-10-30
摘要： A process for the production of detergent range alcohols and ketones by reacting an alkane with a hydroperoxide in the presence of a transition metal porphyrin catalyst is described. Preferred hydroperoxides include cumene hydroperoxide and tertiary butyl hydroperoxide. The transition metal porphyrin catalyst may be transition metal phthalocyanines, transition metalloporphines and the like. The transition metal itself may be iron, manganese, cobalt and mixtures thereof. Suitable ligands include, but are not limited to imidazoles and lithium borate. Other useful additives include alkali metal perchlorates, such as sodium perchlorate, iodosylbenzene and alkali metal superoxides, such as potassium superoxide, and phase transfer catalysts such as tetrabutyl ammonium bromide.
摘要翻译： 描述了在过渡金属卟啉催化剂存在下通过使烷烃与氢过氧化物反应来生产洗涤剂范围的醇和酮的方法。 优选的氢过氧化物包括氢过氧化枯烯和叔丁基过氧化氢。 过渡金属卟啉催化剂可以是过渡金属酞菁，过渡金属卟啉等。 过渡金属本身可以是铁，锰，钴及其混合物。 合适的配体包括但不限于咪唑和硼酸锂。 其它有用的添加剂包括碱金属高氯酸盐如高氯酸钠，碘代苯和碱金属超氧化物如超氧化钾，以及相转移催化剂如四丁基溴化铵。
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8.发明授权
公开(公告)号：US4910349A
公开(公告)日：1990-03-20
申请号：US94173
申请日：1987-09-08
IPC分类号： C07C29/132
CPC分类号： C07C29/132
摘要： Tertiary butyl alcohol is prepared by the catalytic decomposition of tertiary butyl hydroperoxide, preferably in solution in tertiary butyl alcohol, in the presence of a metal phthalocyanine catalyst promoted with a rhenium compound, such as a phthalocyanine of a metal of Group IB, Group VIIB or Group VIIIB of the Periodic Table (e.g., chloroferric phthalocyanine and rhenium heptoxide-p-dioxane or oxotrichloro-bis-(triphenylphosphine) rhenium V).
摘要翻译： 通过叔丁基过氧化氢的催化分解，优选在叔丁醇的溶液中，在用铼化合物，如IB组金属，ⅦB族金属的酞菁等促进的金属酞菁催化剂的存在下，制备叔丁醇， 元素周期表VIIIB组（例如，氯代酞菁和铼的叔丁醇钌或氧三氯 - 双 - （三苯基膦）铼V）。
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公开(公告)号：US4722919A
公开(公告)日：1988-02-02
申请号：US916075
申请日：1986-10-06
IPC分类号： B01J31/22
CPC分类号： B01J31/223 , B01J31/4092 , B01J2231/72 , B01J2531/56
摘要： Complexes made by reacting propylene glycol with a vanadium compound soluble therein at an elevated temperature. Mild stripping of the water subsequent to complex formation is preferred. The ratio of moles of propylene glycol to gram atoms of vanadium in the complex forming reaction ranges from 7:1 to 20:1.
摘要翻译： 通过使丙二醇与可溶于其中的钒化合物在升高的温度下反应制得的络合物。 复合物形成后水的轻度汽提是优选的。 络合物形成反应中丙二醇与钒原子数的摩尔比为7:1至20:1。
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10.发明授权Purification of propylene oxide by treatment with a selected base and inert salt 失效通过用选择的碱和惰性盐处理来纯化环氧丙烷
公开(公告)号：US4691035A
公开(公告)日：1987-09-01
申请号：US851846
申请日：1986-04-14
IPC分类号： C07D301/32
CPC分类号： C07D301/32
摘要： Methyl formate is removed from propylene oxide by treatment with a selected base such as sodium hydroxide in water and glycerol. Selected inert salts may be added. The rate of methyl formate hydrolysis by selected bases was increased to commercially acceptable levels by addition of the glycerol. The glycerol and inert salts reduced the amount of residual water in the propylene oxide.
摘要翻译： 通过用选择的碱如氢氧化钠在水和甘油中处理，从环氧丙烷中除去甲酸甲酯。 可以加入选择的惰性盐。 通过加入甘油将选择的碱的甲酸甲酯水解速率提高到商业上可接受的水平。 甘油和惰性盐减少环氧丙烷中残留水的量。
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