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US4499281A Substituted triazolylmethyl-oxiranes and their use as intermediates for fungicides 失效
取代的三唑基甲基 - 环氧乙烷及其作为杀真菌剂的中间体

Substituted triazolylmethyl-oxiranes and their use as intermediates for
fungicides
摘要:
A substituted triazolylmethyl-oxirane of the formula ##STR1## in which R is optionally substituted alkyl, aryl or cycloalkyl is prepared by reacting a triazolyl-ketone of the formula ##STR2## with (a) dimethyloxosulphonium methylide of the formula ##STR3## or (b) trimethylsulphonium methylsulphate of the formula[(CH.sub.3).sub.3 S].sup..sym. CH.sub.3 SO.sub.4.sup..crclbar.in the presence of a diluent.The end product can then be reacted with a phenol of the formulaR"--OHto produce known fungicidally active compounds of the formula ##STR4## in which R" is optionally substituted phenyl.
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