发明授权
- 专利标题: Desulfurization of H.sub.2 S-containing gases
- 专利标题(中): 含H2S的气体脱硫
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申请号: US473533申请日: 1983-03-09
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公开(公告)号: US4507274A公开(公告)日: 1985-03-26
- 发明人: Franz J. Broecker , Hans Gettert , Knut Kaempfer
- 申请人: Franz J. Broecker , Hans Gettert , Knut Kaempfer
- 申请人地址: DEX
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DEX
- 优先权: DEX3208695 19820311
- 主分类号: B01D53/86
- IPC分类号: B01D53/86 ; B01J8/02 ; B01J8/04 ; B01J23/22 ; B01J23/88 ; B01J27/00 ; B01J27/232 ; C01B17/04 ; C01B17/02
摘要:
H.sub.2 S-containing gases are desulfurized by direct catalytic oxidation of the H.sub.2 S to elementary sulfur by means of oxygen-containing gases in a tube reactor, with indirect removal of the heat of reaction by means of a coolant and with condensation of the sulfur formed, wherein either the catalyst is present in the jacket space around the tubes and the coolant is present in the tubes of the reactor or the coolant is present in the jacket space around the tubes and the catalyst is present in the tubes of the reactor, and the catalyst fills the tubes of the tube reactor or the jacket space around the tubes over the entire cross-section of the tubes or the jacket space respectively, the exit temperature of the gaseous reaction mixture leaving the tube reactor is kept at 180.degree.-400.degree. C. and the sulfur formed in the tube reactor is separated out of the reaction mixture, obtained in the reactor, in a condensation stage downstream of the reactor.
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