A process for producing cooper foil laminated plates using rolled copper foils made of oxygen-free copper is described. The major feature of the present process is that in laminating a rolled copper foil on an insulating substrate, the rolled copper foil is ground or abraded and immediately brought into contact with water or steam to form a hydrate layer on the surface thereof. This hydrate layer increases the adhesion strength of the rolled copper foil to the insulating substrate through an adhesive, producing a copper foil laminated plate having an adhesion strength sufficiently high for practical use. Thus these copper foil laminated plates are very suitable for use in wiring of electronic devices.