发明授权
US4522960A Controlled gelation on nonaqueous solutions containing low charge
density polyampholytes
失效
含有低电荷密度聚阴离子的非水溶液的控制凝胶化
- 专利标题: Controlled gelation on nonaqueous solutions containing low charge density polyampholytes
- 专利标题(中): 含有低电荷密度聚阴离子的非水溶液的控制凝胶化
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申请号: US638218申请日: 1984-08-06
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公开(公告)号: US4522960A公开(公告)日: 1985-06-11
- 发明人: Dennis G. Peiffer , Robert D. Lundberg
- 申请人: Dennis G. Peiffer , Robert D. Lundberg
- 申请人地址: NJ Florham Park
- 专利权人: Exxon Research & Engineering Co.
- 当前专利权人: Exxon Research & Engineering Co.
- 当前专利权人地址: NJ Florham Park
- 主分类号: C08J3/09
- IPC分类号: C08J3/09 ; C08L39/00
摘要:
A process for gelling a fluid having a viscosity of at least about 50 cps which includes the steps of: forming a solvent system of the nonpolar organic liquid and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system and a viscosity of the solvent system being less than about 100 cps; dissolving a water insoluble, oil soluble terpolymer in the solvent system to form a solution, a concentration of the terpolymer in the solution being about 0.2 to about 10 weight percent and a viscosity of the solution being less than about 2000 cps, the terpolymer having the formula: ##STR1## wherein x is about 40 to about 98 mole %, y is about 1 to about 50 mole %, and z is about 1 to about 50 mole %, wherein y and z are less than 60 mole %, and M is an amine or a metal cation selected from the group consisting of antimony tin, lead, Groups IA, IIA, IB and IIB of the Periodic Table of Elements; and adding about 5 to about 500 volume percent water to the solution of the terpolymer, said water being immiscible with the solution of the terpolymer, the polar cosolvent transferring from the nonpolar organic liquid to the water thereby causing the viscosity of the organic liquid to increase to at least 5000 cps.
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