发明授权
- 专利标题: Process for the preparation of polyesters from aliphatic dicarboxylic acids and polyalkylpiperidyl diols
- 专利标题(中): 从脂族二羧酸和聚烷基哌啶二醇制备聚酯的方法
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申请号: US626507申请日: 1984-06-29
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公开(公告)号: US4535145A公开(公告)日: 1985-08-13
- 发明人: Eduard Troxler , Thomas Kainmuller , Rudolf Maul
- 申请人: Eduard Troxler , Thomas Kainmuller , Rudolf Maul
- 申请人地址: NY Ardsley
- 专利权人: Ciba-Geigy Corporation
- 当前专利权人: Ciba-Geigy Corporation
- 当前专利权人地址: NY Ardsley
- 优先权: CHX3765/83 19830708
- 主分类号: C08G63/00
- IPC分类号: C08G63/00 ; C08G63/66 ; C08G63/68 ; C08G63/685 ; C08G63/688 ; C08G63/82 ; C08G63/85 ; C08G73/06 ; C08G63/44 ; C08G73/16
摘要:
The invention relates to a novel process for the preparation of compounds of the formula I ##STR1## by polycondensation of a diol of the formula II ##STR2## with a dicarboxylic acid ester of the formula III ##STR3## In the above formulae, the substituents and symbols R.sub.1, R.sub.2, R.sub.3 and n are as defined in claim 1.The process comprises stirring the reaction medium which contains an excess of 2 to 50 mol. %, based on the diol of formula II, of the dicarboxylic acid ester of the formula III, in the presence of at least 0.03 mol. % of a suitable catalyst, until the bulk of the alkanol of the formula R.sub.3 OH formed during the reaction is distilled off, under a pressure of 0.7 to 1.3 bar, and thereafter stirring under a pressure of less than 5 mbar, in the temperature range from 100.degree. to 170.degree. C., and subsequently working up the resultant melt in conventional manner.