公开(公告)号：US4535145A

公开(公告)日：1985-08-13

申请号：US626507

申请日：1984-06-29

申请人： Eduard Troxler ,  Thomas Kainmuller ,  Rudolf Maul

发明人： Eduard Troxler ,  Thomas Kainmuller ,  Rudolf Maul

IPC分类号： C08G63/00 ,  C08G63/66 ,  C08G63/68 ,  C08G63/685 ,  C08G63/688 ,  C08G63/82 ,  C08G63/85 ,  C08G73/06 ,  C08G63/44 ,  C08G73/16

CPC分类号： C08G63/6856 ,  C08G63/85

摘要： The invention relates to a novel process for the preparation of compounds of the formula I ##STR1## by polycondensation of a diol of the formula II ##STR2## with a dicarboxylic acid ester of the formula III ##STR3## In the above formulae, the substituents and symbols R.sub.1, R.sub.2, R.sub.3 and n are as defined in claim 1.The process comprises stirring the reaction medium which contains an excess of 2 to 50 mol. %, based on the diol of formula II, of the dicarboxylic acid ester of the formula III, in the presence of at least 0.03 mol. % of a suitable catalyst, until the bulk of the alkanol of the formula R.sub.3 OH formed during the reaction is distilled off, under a pressure of 0.7 to 1.3 bar, and thereafter stirring under a pressure of less than 5 mbar, in the temperature range from 100.degree. to 170.degree. C., and subsequently working up the resultant melt in conventional manner.

摘要翻译： 本发明涉及通过式II（Ⅱ）的二醇与式III的二羧酸酯缩合制备式I化合物（I）的新方法（IMAGE III）在上式中，取代基和符号R1，R2，R3和n如权利要求1中所定义。该方法包括搅拌含有过量2-50mol的反应介质。 ％，基于式II的二元醇，式III的二羧酸酯在至少0.03mol的存在下反应。 ％的合适的催化剂，直到在反应中形成的式R3OH的烷醇的主体在0.7至1.3巴的压力下蒸馏出，然后在小于5毫巴的压力下搅拌，温度范围为 100℃至170℃，然后以常规方式处理所得的熔体。

公开(公告)号：US5401845A

公开(公告)日：1995-03-28

申请号：US212756

申请日：1994-03-11

申请人： Rita Pitteloud ,  Peter Hofmann ,  Rudolf Maul ,  Volker Schenk ,  Eduard Troxler ,  Horst Zinke

发明人： Rita Pitteloud ,  Peter Hofmann ,  Rudolf Maul ,  Volker Schenk ,  Eduard Troxler ,  Horst Zinke

IPC分类号： C07F9/145 ,  C07F9/146 ,  C07F9/59 ,  C08K5/52 ,  C08K5/526 ,  C08K5/529 ,  C08L23/00 ,  C08L101/00

CPC分类号： C08K5/526 ,  C07F9/145 ,  C07F9/146 ,  C07F9/591 ,  C07F9/595

摘要： Compounds of the formula I ##STR1## in which x is 1, 2 or 3, and, if x=1, R.sup.1 is C.sub.1 -C.sub.30 alkyl, C.sub.1 -C.sub.18 alkyl substituted by halogen, --COOR.sup.2, --CN, --NR.sup.3 R.sup.4 or by --CONR.sup.3 R.sup.4, C.sub.2 -C.sub.18 alkyl which is interrupted by --NR.sup.5 --, --O-- or --S--, C.sub.3 -C.sub.18 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl-C.sub.1 -C.sub.4 alkyl, phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.12 alkyl, halogen, phenyl-C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, or R.sub.1 is naphthyl, a radical of the formula ##STR2## R.sub.2, R.sub.3, R.sub.4 and R.sub.5, independently of one another, are hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl or phenyl-C.sub.1 -C.sub.4 alkyl, R.sup.6 is hydrogen, methyl, allyl or benzyl, R.sup.7 is hydrogen or --OR.sup.9, R.sup.8 is hydrogen or methyl, R.sup.9 is hydrogen or C.sub.1 -C.sub.30 alkyl, R.sup.10 and R.sup.11, independently of one another, are hydrogen or C.sub.1 -C.sub.8 alkyl, and n is 3-6, with the proviso that R.sup.1 is not a phenyl radical which is substituted in both ortho-positions to the carbon atom bonded to the oxygen atom,if x=2, R.sup.1 is C.sub.2 -C.sub.18 alkylene, C.sub.2 -C.sub.18 alkylene which is interrupted by --NR.sup.5, --O-- or --S--, or is a ##STR3## radical, and, if x=3, R.sup.1 is C.sub.4 -C.sub.12 alkanetriyl or a ##STR4## group in which m is 1-4, are suitable as stabilizers for organic materials which are sensitive to thermal, oxidative and/or photoinduced degradation.

摘要翻译： 式I的化合物（I）其中x为1,2或3，如果x = 1，则R1为C1-C30烷基，被卤素取代的C1-C18烷基，-COOR2，-CN，-NR3R4或 被-CONR 3 R 4，被-NR 5 - ，-O-或-S-，C 3 -C 18烯基，C 5 -C 12环烷基，苯基-C 1 -C 4烷基，未被取代或被C 1 -C 12烷基取代的苯基，卤素， 苯基-C 1 -C 4烷基和/或C 1 -C 4烷氧基，或者R 1为萘基，R 2，R 3，R 4和R 5彼此独立地为氢，C 1 -C 18烷基， C 1 -C 12烷基或苯基-C 1 -C 4烷基，R 6是氢，甲基，烯丙基或苄基，R 7是氢或-OR 9，R 8是氢或甲基，R 9是氢或C 1 -C 30烷基，R 10和R 11彼此独立地是氢 或C 1 -C 8烷基，n为3-6，条件是R 1不是在与氧原子键合的碳原子的两个邻位被取代的苯基，如果x = 2，则R1为C2-C18亚烷基 被-NR 5，-O-或-S-中断的C 2 -C 18亚烷基，或者是a 如果x = 3，则R 1为C 4 -C 12烷基三乙基或其中m为1-4的基团，适用于对热，氧化和/或光诱导降解敏感的有机材料的稳定剂 。

公开(公告)号：US5322871A

公开(公告)日：1994-06-21

申请号：US49647

申请日：1993-04-20

申请人： Rita Pitteloud ,  Peter Hofmann ,  Rudolf Maul ,  Volker Schenk ,  Eduard Troxler ,  Horst Zinke

发明人： Rita Pitteloud ,  Peter Hofmann ,  Rudolf Maul ,  Volker Schenk ,  Eduard Troxler ,  Horst Zinke

IPC分类号： C07F9/145 ,  C07F9/146 ,  C07F9/59 ,  C08K5/52 ,  C08K5/526 ,  C08K5/529 ,  C08L23/00 ,  C08L101/00

CPC分类号： C08K5/526 ,  C07F9/145 ,  C07F9/146 ,  C07F9/591 ,  C07F9/595

摘要： Compounds of the formula I ##STR1## in which x is 1, 2 or 3, and, if x=1, R.sup.1 is C.sub.1 -C.sub.30 alkyl, C.sub.1 -C.sub.18 alkyl substituted by halogen, --COOR.sup.2, --CN, --NR.sup.3 R.sup.4 or by --CONR.sup.3 R.sup.4, C.sub.2 -C.sub.18 alkyl which is interrupted by --NR.sup.5 --, --O-- or --S--, C.sub.3 -C.sub.18 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl-C.sub.1 -C.sub.4 alkyl, phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.12 alkyl, halogen, phenyl-C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, or R.sub.1 is naphthyl, a radical of the formula ##STR2## R.sub.2, R.sub.3, R.sub.4 and R.sub.5, independently of one another, are hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl or phenyl-C.sub.1 -C.sub.4 alkyl, R.sup.6 is hydrogen, methyl, allyl or benzyl, R.sup.7 is hydrogen or --OR.sup.9, R.sup.8 is hydrogen or methyl, R.sup.9 is hydrogen or C.sub.1 -C.sub.30 alkyl, R.sup.10 and R.sup.11, independently of one another, are hydrogen or C.sub.1 -C.sub.8 alkyl, and n is 3-6, with the proviso that R.sup.1 is not a phenyl radical which is substituted in both ortho-positions to the carbon atom bonded to the oxygen atom, if x=2, R.sup.1 is C.sub.2 -C.sub.18 alkylene, C.sub.2 -C.sub.18 alkylene which is interrupted by --NR.sup.5 --, --O-- or --S--, or is a ##STR3## radical, and, if x=3, R.sup.1 is C.sub.4 -C.sub.12 alkanetriyl or a ##STR4## group in which m is 1-4, are suitable as stabilisers for organic materials which are sensitive to thermal, oxidative and/or photoinduced degradation.

摘要翻译： 式I的化合物（I）其中x为1,2或3，如果x = 1，则R1为C1-C30烷基，被卤素取代的C1-C18烷基，-COOR2，-CN，-NR3R4或 被-CONR 3 R 4，被-NR 5 - ，-O-或-S-，C 3 -C 18烯基，C 5 -C 12环烷基，苯基-C 1 -C 4烷基，未被取代或被C 1 -C 12烷基取代的苯基，卤素， 苯基-C 1 -C 4烷基和/或C 1 -C 4烷氧基，或者R 1为萘基，R 2，R 3，R 4和R 5彼此独立地为氢，C 1 -C 18烷基， C 1 -C 12烷基或苯基-C 1 -C 4烷基，R 6是氢，甲基，烯丙基或苄基，R 7是氢或-OR 9，R 8是氢或甲基，R 9是氢或C 1 -C 30烷基，R 10和R 11彼此独立地是氢 或C 1 -C 8烷基，n为3-6，条件是R 1不是在与氧原子键合的碳原子的两个邻位被取代的苯基，如果x = 2，则R1为C2-C18亚烷基 被-NR 5 - ，-O-或-S-中断的C 2 -C 18亚烷基，或者是a 如果x = 3，则R 1为C 4 -C 12烷基三乙基或其中m为1-4的基团，适用于对热，氧化和/或光诱导降解敏感的有机材料的稳定剂 。

公开(公告)号：US5171873A

公开(公告)日：1992-12-15

申请号：US861704

申请日：1992-04-01

申请人： Thomas Kainmuller ,  Rudolf Maul

发明人： Thomas Kainmuller ,  Rudolf Maul

IPC分类号： B01J31/04 ,  C07B61/00 ,  C07F9/40

CPC分类号： C07F9/4056

摘要： A process for the preparation of hydroxybenzylphosphonates of forula ##STR1## by reacting Mannich base of formula ##STR2## with as trialkyl phosphite of formula ##STR3## wherein R.sub.1 and R.sub.2 are each independently of the other C.sub.1 -C.sub.12 alkyl or, when taken together form a piperidinyl or morpholinyl radical, and R.sub.5, R.sub.6 and R.sub.7 are each independently of one another C.sub.1 -C.sub.4 alkyl, which reaction is carried out in the presence of a carboxylic anhydride (IV).The compounds of formula I may suitably be used as processing stabilizers for plastics.

摘要翻译： 通过使式（I）的曼尼希碱与式（III）的亚磷酸三烷基酯反应制备式（I）的羟基苄基膦酸盐的方法，其中R1和R2各自独立地为C1 -C 12烷基，或者当一起形成哌啶基或吗啉基时，R 5，R 6和R 7各自独立地为C 1 -C 4烷基，该反应在羧酸酐（IV）的存在下进行。 式I化合物可适当地用作塑料的加工稳定剂。

公开(公告)号：US3971817A

公开(公告)日：1976-07-27

申请号：US495357

申请日：1974-08-07

申请人： Hans Wolf Jung ,  Rudolf Maul ,  Siegfried Kintopf ,  Wilfried Kloss ,  Reinhard Knapp

发明人： Hans Wolf Jung ,  Rudolf Maul ,  Siegfried Kintopf ,  Wilfried Kloss ,  Reinhard Knapp

IPC分类号： C07B61/00 ,  C07F7/22

CPC分类号： C07F7/2216

摘要： In the manufacture of monomethyl-tin trichloride by disproportionation of tin tetrachloride with dimethyl-tin dichloride, high yields are achieved by employing phosphines, arsines and stibines or onium compounds of elements of the fifth main group in the periodic system as the catalyst, optionally together with a co-catalyst.

摘要翻译： 在通过二氯甲烷二氯化锡歧化四氯化锡制造单三氯化锡的过程中，通过在周期系统中使用第五主族的元素的膦，胂和锑化合物或鎓化合物作为催化剂，任选地一起 与助催化剂。

公开(公告)号：US5276161A

公开(公告)日：1994-01-04

申请号：US582292

申请日：1990-09-13

申请人： Helmut Prestel ,  Rudolf Maul

发明人： Helmut Prestel ,  Rudolf Maul

IPC分类号： B01J23/40 ,  C01B3/00 ,  C07B61/00 ,  C07D249/20 ,  C09K3/00 ,  C07D249/18

CPC分类号： C07D249/20 ,  Y02E60/324

摘要： 2-(2-Hydroxyphenyl)-2H-benzotriazoles of the formula ##STR1## in which R is hydrogen, C.sub.1 -C.sub.12 alkyl or C.sub.1 -C.sub.4 alkoxy, R.sub.1 is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.6 cycloalkyl, phenyl or phenyl-C.sub.1 -C.sub.4 alkyl and R.sub.2 is C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.6 cycloalkyl, phenyl, phenyl-C.sub.1 -C.sub.4 alkyl or a group --C.sub.n H.sub.2n --COOR.sub.3, in which n is 0 to 4 and R.sub.3 is hydrogen or C.sub.1 -C.sub.12 alkyl, can be prepared particularly advantageously by catalytic hydrogenation of a suitable o-nitroazo compound in the presence of a Pt, Pd, Pt/Pd or Rh hydrogenation catalyst and an alkylenediamine or an acyclic or cyclic polyalkylene polyamine in a halogenated or nonhalogenated aromatic hydrocarbon as solvent.

摘要翻译： 其中R是氢，C 1 -C 12烷基或C 1 -C 4烷氧基，R 1是氢，C 1 -C 12烷基，C 5 -C 6环烷基，苯基或苯基-C 1 -C 4烷氧基的2-（2-羟基苯基）-2H-苯并三唑 C4烷基和R2是C1-C12烷基，C5-C6环烷基，苯基，苯基-C1-C4烷基或基团-CnH2n-COOR3，其中n为0-4，R3为氢或C1-C12烷基，可以特别有利地通过催化 在Pt，Pd，Pt / Pd或Rh氢化催化剂和烷基二胺或非环状或环状聚亚烷基多胺作为溶剂的卤代或非卤代芳族烃存在下氢化合适的邻硝基偶氮化合物。

公开(公告)号：US4052426A

公开(公告)日：1977-10-04

申请号：US659865

申请日：1976-02-20

申请人： Wolfgang Wehner ,  Rudolf Maul ,  Hans-Wolf Jung

发明人： Wolfgang Wehner ,  Rudolf Maul ,  Hans-Wolf Jung

IPC分类号： C07F9/02 ,  C07F7/22

CPC分类号： C07F9/02

摘要： Complexes composed of alkylphosphines or of alkylphosphonium chlorides and tin tetrachloride are good catalysts for the preparation of dimethyl-tin dichloride from tin and methyl chloride in the presence of sulphones and carbonates as solvents.

公开(公告)号：US5235086A

公开(公告)日：1993-08-10

申请号：US759987

申请日：1991-09-16

申请人： Rudolf Maul ,  Volker Schenk

发明人： Rudolf Maul ,  Volker Schenk

IPC分类号： C07F9/145

CPC分类号： C07F9/145

摘要： A process for the preparation of tris-(2,4-ditert-butylphenyl) phosphite from 2,4-ditert-butylphenol and phosphorus trichloride in the presence of catalysts, which comprises carrying out the reaction in an at least three-stage process in which the 2,4-ditert-butylphenol and 40-100% of the catalyst are combined in a preliminary stage and are brought together with the phosphorus trichloride in a first stage, these being allowed to react under normal pressure and at temperatures of 55.degree. to 70.degree. C. for a dwell time of 15 to 40 minutes, the reaction mixture is then reacted in a second stage under normal pressure and at temperatures of over 140.degree. C., remaining amounts of catalyst being added to the first and/or second reaction stage, the reaction mixture is then kept under reduced pressure at temperatures of at least 186.degree. C. in a third reaction stage, and the tris-(2,4-ditert-butylphenyl) phosphite is then isolated from the reaction mixture, the process being carried out in the absence of solvents.

摘要翻译： 一种在催化剂存在下由2,4-二叔丁基苯酚和三氯化磷制备三（2,4-二叔丁基苯基）亚磷酸酯的方法，包括在至少三步法中进行反应 其中2,4-二叔丁基苯酚和40-100％的催化剂在初级阶段合并，并在第一阶段与三氯化磷一起使其在常压下和在55℃的温度下反应 至70℃，停留时间为15至40分钟，然后将反应混合物在常压下和在超过140℃的温度的第二阶段中反应，将催化剂的剩余量加入到第一和/或 在第二反应阶段，然后在第三反应阶段将反应混合物在至少186℃的温度下保持在减压下，然后从反应混合物中分离出三 - （2,4-二叔丁基苯基）亚磷酸酯， 该过程正在进行中 溶剂。

公开(公告)号：US4214088A

公开(公告)日：1980-07-22

申请号：US958760

申请日：1978-11-08

申请人： Gerd Abeler ,  Rudolf Maul

发明人： Gerd Abeler ,  Rudolf Maul

IPC分类号： C07D211/90 ,  C08K5/00 ,  C08K5/09 ,  C08K5/098 ,  C08K5/34 ,  C08K5/3412 ,  C08K5/3432 ,  C08K5/378 ,  C08L1/00 ,  C08L27/00 ,  C08L27/04 ,  C08L27/06 ,  C08L33/00 ,  C08L33/02 ,  C08L101/04 ,  C07D213/80

CPC分类号： C08K5/3432 ,  C07D211/90 ,  C08K5/005 ,  C08K5/378

摘要： Stabilization of chlorine-containing thermoplasts with 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylic acid esters alone or, in particular, together with a metal-containing stabilizer as synergist.

摘要翻译： 单独使用1,4-二氢-2,6-二甲基吡啶-3,5-二羧酸酯，特别是与作为增效剂的含金属稳定剂一起使含氯热塑性淀粉稳定化。

公开(公告)号：US5086173A

公开(公告)日：1992-02-04

申请号：US699067

申请日：1991-05-13

申请人： Wolfgang Tritschler ,  Heinz Steiner ,  Helmut Prestel ,  Rudolf Maul

发明人： Wolfgang Tritschler ,  Heinz Steiner ,  Helmut Prestel ,  Rudolf Maul

IPC分类号： C07D251/46 ,  C08K5/37

CPC分类号： C07D251/46

摘要： A process for the preparation of compounds of formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.6 cycloalkyl or phenyl, and R.sub.3 and R.sub.4 are each independently of the other C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.6 cycloalkyl, phenyl, phenyl which is substituted by C.sub.1 -C.sub.6 alkyl and/or hydroxy, or phenyl-C.sub.1 -C.sub.4 alkyl. The process comprises reacting a compound of formula III ##STR2## with a nitrite in aqueous or aqueous/organic medium to a compound of formula II ##STR3## extracting said compound of formula II from the reaction solution with a solvent, hydrogenating said compound, without isolation, in the cited solvent and in the presence of a palladium catalyst, to the corresponding p-aminophenol, and reacting said aminophenol, without isolation, with cyanuric chloride and a compound of formula HSR.sub.3 or HSR.sub.4 or a mixture of compounds of formulae HSR.sub.3 and HSR.sub.4. The products are obtained in high yield and purity.

摘要翻译： 制备式I化合物的方法（I）其中R 1和R 2各自独立于其它的氢，C 1 -C 12烷基，C 5 -C 6环烷基或苯基，且R 3和R 4各自独立地为其它的C1- C 1 -C 6烷基，C 5 -C 6环烷基，苯基，被C 1 -C 6烷基和/或羟基取代的苯基或苯基-C 1 -C 4烷基。 该方法包括使式III化合物（III）与水性或水/有机介质中的亚硝酸盐反应到式II化合物（II），用溶剂从反应溶液中提取所述式II化合物 在所述溶剂中并在钯催化剂存在下，将所述化合物氢化为相应的对氨基苯酚，并将所述氨基苯酚与氰尿酰氯和式HSR3或HSR4的化合物或其混合物 的式HSR3和HSR4的化合物。 以高产率和纯度获得产品。