发明授权
- 专利标题： Rhodium-phosphine complex
- 专利标题（中）： 铑膦络合物
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申请号： US714281申请日： 1985-03-21
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公开(公告)号： US4604474A公开(公告)日： 1986-08-05
- 发明人: Hidenori Kumobayashi , Susumu Akutagawa
- 申请人： Hidenori Kumobayashi , Susumu Akutagawa
- 申请人地址： JPX Tokyo
- 专利权人： Takasago Perfumery Co., Ltd.
- 当前专利权人： Takasago Perfumery Co., Ltd.
- 当前专利权人地址： JPX Tokyo
- 优先权： JPX59-53600 19840322
- 主分类号： C07F9/50
- IPC分类号： C07F9/50 ; B01J31/00 ; B01J31/28 ; C07B61/00 ; C07C45/51 ; C07C209/68 ; C07F15/00
摘要：
A novel rhodium-phosphine complex represented by the formula[Rh(p-Tolyl BINAP).sub.2 ].sup.+ Y.sup.-wherein p-Tolyl BINAP represents 2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl, and Y represents ClO.sub.4, PF.sub.6, BF.sub.4 or PCl.sub.6 is described. This complex can be used as a catalyst for various organic syntheses and also for asymmetric syntheses such as an asymmetric isomerization reaction and an asymmetric hydrogenation reaction. Due to its high activity, the complex is very useful as a catalyst.
公开/授权文献
- US5676626A Rocking exerciser 公开/授权日：1997-10-14
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