摘要:
A process for producing an optically active alcohol represented by formula (I): ##STR1## wherein R.sub.1 is an alkyl group having from 2 to 11 carbon atoms, an alkenyl group having from 3 to 11 carbon atoms, an alkadienyl group having from 6 to 11 carbon atoms, a cyclohexyl group, an cyclohexylmethyl group, or a cyclohexylethyl group, provided that the olefin in the alkenyl group or alkadienyl group is not conjugated to the olefin at the 2-position thereof; and * means an asymmetric carbon atom,is disclosed, comprising subjecting an olefinic alcohol represented by formula (II): ##STR2## wherein R.sub.1 is the same as defined above to asymmetric hydrogenation in the presence of, as a catalyst, a ruthenium-optically active phosphine complex.According to the process of the invention, the desired optically active alcohols which are useful not only as intermediates for the manufacture of perfumes and vitamin E but also as liquid crystal materials can be produced with high optical purities.
摘要:
A perfume composition is described, which contains at least one compound of bicyclo[2,2,2]octane and bicyclo[2,2,2]octene derivatives represented by the general formula (I) ##STR1## wherein the symbols are the same as defined hereinbefore.
摘要:
1,2,6-Trimethyltricyclo[5,3,2,0.sup.2,7 ]dodeca-5-one having the formula (I) ##SPC1##and a process for producing this compound. This compound is useful as a perfume.
摘要:
PRODUCTION OF SQUALENE-TYPE-HYDROCARBONS BY DIMERIZING CONJUGATED DIENE COMPOUNDS IN A ALIPHATIC ALCOHOL IN THE PRESENCE OF A CATALYST CONSISTING OF BIS-CYCLOOCTADIENE-NICKEL AND A TRI-ALKYL PHOSPHINE.
摘要:
An actuator for liquid ejection which is provided with a plug for closing the ejection spout disposed at the distal portion thereof. This actuator is capable of preventing a residual liquid which is left inside the actuator after an ejection operation from being contacted with an outer atmosphere, thereby preventing the denaturing or degradation of the liquid. Further, it is capable of preventing a ejection spout from being stopped up and of preventing a filmy cover or block to be made. This plug is mounted on an elastic rod-like member disposed in and along the liquid-discharging passage, and is adapted to be moved backward, thus opening the ejection spout as the elastic rod-like member is forced to bend by an actuating rod when the actuator is pushed downward.
摘要:
A method for preparing green aroma compounds is disclosed wherein raw soybeans are ground at a temperature of 60.degree. C. or less, unsaturated fatty acid are added thereto form a mixture, and the mixture is stirred at a temperature of 5.degree. to 60.degree. C. while supplying air or oxygen to form green aroma compounds.
摘要:
A 1,1,4,4-tetraphenyl-1,3-butadiene derivatives represented by formula (I): ##STR1## wherein R.sub.1 represents a di-lower alkylamino group, and R.sub.2 represents a hydrogen atom or a di-lower alkylamino group, is disclosed, which has useful characteristics such as excellent static charge retention ability. An electrophotographic light-sensitive material using the foregoing derivative can satisfy the requirements, e.g., for high sensitivity, low residual potential, less light fatigue even after repeated use, and excellent durability.
摘要:
A perfume composition is disclosed, containing methyl l-3,7-dimethyl-7-hydroxyoctylideneanthranilate of the following formula (I): ##STR1## The perfume composition of the invention is less allergenic and safer than those containing the corresponding d- or dl-form. Further, the perfume composition has a less irritating odor and imparts a clean and green note.