Process for producing optically active alcohols
    1.
    发明授权
    Process for producing optically active alcohols 失效
    光学活性醇的制造方法

    公开(公告)号:US4962242A

    公开(公告)日:1990-10-09

    申请号:US66164

    申请日:1987-06-25

    IPC分类号: C07C29/17

    CPC分类号: C07C29/172 C07B2200/07

    摘要: A process for producing an optically active alcohol represented by formula (I): ##STR1## wherein R.sub.1 is an alkyl group having from 2 to 11 carbon atoms, an alkenyl group having from 3 to 11 carbon atoms, an alkadienyl group having from 6 to 11 carbon atoms, a cyclohexyl group, an cyclohexylmethyl group, or a cyclohexylethyl group, provided that the olefin in the alkenyl group or alkadienyl group is not conjugated to the olefin at the 2-position thereof; and * means an asymmetric carbon atom,is disclosed, comprising subjecting an olefinic alcohol represented by formula (II): ##STR2## wherein R.sub.1 is the same as defined above to asymmetric hydrogenation in the presence of, as a catalyst, a ruthenium-optically active phosphine complex.According to the process of the invention, the desired optically active alcohols which are useful not only as intermediates for the manufacture of perfumes and vitamin E but also as liquid crystal materials can be produced with high optical purities.

    摘要翻译: 一种制备由式(I)表示的光学活性醇的方法:其中R1是具有2至11个碳原子的烷基,具有3至11个碳原子的链烯基,具有 环己基,环己基甲基或环己基乙基,条件是烯基或链二烯基中的烯烃在2-位没有与烯烃共轭; 和*表示不对称碳原子,包括使式(II)表示的烯属醇:其中R 1与上述定义相同,在作为催化剂的存在下进行不对称氢化 钌 - 光学活性膦配合物。 根据本发明的方法,不仅可用于制造香料和维生素E,而且用作液晶材料的中间体所需的光学活性醇可以以高光学纯度生产。

    Actuator for liquid ejection
    7.
    发明授权
    Actuator for liquid ejection 失效
    液体喷射执行器

    公开(公告)号:US5205443A

    公开(公告)日:1993-04-27

    申请号:US810411

    申请日:1991-12-20

    IPC分类号: B05B1/34 B65D83/16

    CPC分类号: B65D83/207 B05B1/3442

    摘要: An actuator for liquid ejection which is provided with a plug for closing the ejection spout disposed at the distal portion thereof. This actuator is capable of preventing a residual liquid which is left inside the actuator after an ejection operation from being contacted with an outer atmosphere, thereby preventing the denaturing or degradation of the liquid. Further, it is capable of preventing a ejection spout from being stopped up and of preventing a filmy cover or block to be made. This plug is mounted on an elastic rod-like member disposed in and along the liquid-discharging passage, and is adapted to be moved backward, thus opening the ejection spout as the elastic rod-like member is forced to bend by an actuating rod when the actuator is pushed downward.

    摘要翻译: 一种用于液体喷射的致动器,其具有用于关闭设置在其远端部分处的喷射口的塞子。 该致动器能够防止在喷射操作之后残留在致动器内的残留液体与外部气氛接触,从而防止液体变性或劣化。 此外,能够防止喷射口停止,防止膜膜或块被制造。 该插头安装在沿着液体排放通道设置并沿着液体排出通道的弹性棒状构件上,并且适于向后移动,从而当弹性杆状构件被致动杆强制弯曲时打开喷射口, 致动器被向下推。

    Method for preparing green aroma compounds
    8.
    发明授权
    Method for preparing green aroma compounds 失效
    绿色香气化合物的制备方法

    公开(公告)号:US4769243A

    公开(公告)日:1988-09-06

    申请号:US937631

    申请日:1986-12-03

    摘要: A method for preparing green aroma compounds is disclosed wherein raw soybeans are ground at a temperature of 60.degree. C. or less, unsaturated fatty acid are added thereto form a mixture, and the mixture is stirred at a temperature of 5.degree. to 60.degree. C. while supplying air or oxygen to form green aroma compounds.

    摘要翻译: 公开了一种制备绿色香气化合物的方法,其中将生大豆在60℃或更低的温度下研磨,将不饱和脂肪酸加入其中形成混合物,并将混合物在5℃至60℃的温度下搅拌 同时供应空气或氧气以形成绿色香气化合物。