Invention Grant
- Patent Title: Oxidation of organic compounds using ceric ions in aqueous trifluoromethanesulfonic acid
- Patent Title (中): 在三氟甲磺酸水溶液中氧化有机化合物
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Application No.: US859565Application Date: 1986-05-05
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Publication No.: US4647349APublication Date: 1987-03-03
- Inventor: Robert P. Kreh , Robert M. Spotnitz
- Applicant: Robert P. Kreh , Robert M. Spotnitz
- Applicant Address: NY New York
- Assignee: W. R. Grace & Co.
- Current Assignee: W. R. Grace & Co.
- Current Assignee Address: NY New York
- Main IPC: C25B3/02
- IPC: C25B3/02 ; C07B41/06 ; C07C45/28 ; C07C45/30 ; C07C46/04 ; C07C47/52 ; C07C49/76 ; C07C205/47 ; C25B3/00
Abstract:
A process for oxidizing aromatic and alkyl substituted aromatic compounds to carbonyl containing compounds by contacting an aromatic and alkyl aromatic compound with an aqueous solution of ceric trifluoromethanesulfonate having from at least 0.75 to 7 molar concentration of free acid of trifluoromethanesulfonic acid and at least 0.2 molar cerium ion concentration. The present process provides a highly effective means of forming the desired carbonyl containing product in good yields and high selectivity.
Public/Granted literature
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