发明授权
- 专利标题: Dehydrocyclization process
- 专利标题(中): 脱氢环化过程
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申请号: US426376申请日: 1982-09-29
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公开(公告)号: US4650565A公开(公告)日: 1987-03-17
- 发明人: Robert L. Jacobson , Lawrence W. Jossens
- 申请人: Robert L. Jacobson , Lawrence W. Jossens
- 申请人地址: CA San Francisco
- 专利权人: Chevron Research Company
- 当前专利权人: Chevron Research Company
- 当前专利权人地址: CA San Francisco
- 主分类号: B01J29/068
- IPC分类号: B01J29/068 ; C10G35/095 ; C10G35/06 ; C07C2/52
摘要:
A process is disclosed wherein a naphtha feed is contacted in a reaction vessel with a dehydrocyclization catalyst comprising a large-pore zeolite containing at least one Group VIII metal to produce an aromatics product and a gaseous stream, the aromatics product is separated from the gaseous stream and is passed through a molecular sieve which adsorbs paraffins present in the aromatics product, then the gaseous stream is used to strip the paraffins from the molecular sieve, and the gaseous stream and the paraffins are recycled to the reaction vessel. Preferably, the dehydrocyclization catalyst comprises a type L zeolite containing from 8% to 15% by weight barium and from 0.6% to 1.0% by weight platinum, wherein at least 80% of the crystals of the type L zeolite are larger than 1000 Angstroms, and an inorganic binder selected from the group consisting of silica, alumina, and aluminosilicates.
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