发明授权
- 专利标题: Catalyst for the polymerization of olefins
- 专利标题(中): 用于烯烃聚合的催化剂
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申请号: US932047申请日: 1986-11-18
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公开(公告)号: US4686200A公开(公告)日: 1987-08-11
- 发明人: Minoru Terano , Hirokazu Soga , Masuo Inoue , Katsuyoshi Miyoshi
- 申请人: Minoru Terano , Hirokazu Soga , Masuo Inoue , Katsuyoshi Miyoshi
- 申请人地址: JPX
- 专利权人: Toho Titanium Co., Ltd.
- 当前专利权人: Toho Titanium Co., Ltd.
- 当前专利权人地址: JPX
- 优先权: JPX60-263863 19851126; JPX60-290838 19851225; JPX61-10250 19860122
- 主分类号: C08F4/64
- IPC分类号: C08F4/64 ; C08F4/65 ; C08F10/00
摘要:
A catalyst for the polymerization of olefins which comprises:(A) a solid catalyst component prepared by bringing a co-ground product of a substance (a) obtained by reacting magnesium with at least two molar proportion of an alkyl monohalide in the absence of a solvent but in the presence of iodine and a dialkyl phthalate (b) and optionally existing titanium tetrachloride (c) into contact with titanium tetrachloride in the presence or absence of an aromatic hydrocarbon and/or halohydrocarbon.(B) a 2,6-dialkyl- or 2,2,6,6-tetraalkyl-piperidine derivative, and(C) an organoaluminum compound selected from a trialkyl aluminum, a dialkylaluminum halide and an alkylaluminum dihalide, as well as the solid catalyst component (A) for the catalyst. This catalyst characterized by the use of the specific solid catalyst component exhibits a high polymerization activity combined with stereospecific performance over a prolonged polymerization time and is free from any problem of corrosion and odor in the resultant polymer.