发明授权
US4694060A Process for the treatment of polyorganosilazanes and/or of polyorgano(disilyl)silazanes by means of a treatment of polyorganosilazanes with a catalyst system comprising an ionic inorganic salt and a complexing compound 失效
通过用包含离子无机盐和络合化合物的催化剂体系处理聚有机硅氮烷来处理聚有机硅氮烷和/或聚有机(二甲硅烷基)硅氮烷的方法

Process for the treatment of polyorganosilazanes and/or of
polyorgano(disilyl)silazanes by means of a treatment of
polyorganosilazanes with a catalyst system comprising an ionic
inorganic salt and a complexing compound
摘要:
A process for the treatment of polyorganosilazanes and/or polyorgano(disilyl)silazanes with an effective quantity of a catalyst system comprising (i) an ionic inorganic salt of the formula M.sup.30 A.sup.-, and (II) a compound capable of complexing with the cation M.sup.+ of the salt. The M.sup.+ cation is a metal ion or a quaternary ammonium ion, and A.sup.- is a compatible anion.The polysilazanes are selected from organopolysilazanes and organopoly(disilyl)silazanes. When treated in this manner, the polysilazanes are characterized by good thermal behavior and can, in particular, be used, after pyrolysis, as precursors of ceramic products.
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