发明授权
US4749555A Process for the selective removal of hydrogen sulphide and carbonyl sulfide from light hydrocarbon gases containing carbon dioxide 失效
从含有二氧化碳的轻烃气体中选择性除去硫化氢和硫化羰的方法

  • 专利标题: Process for the selective removal of hydrogen sulphide and carbonyl sulfide from light hydrocarbon gases containing carbon dioxide
  • 专利标题(中): 从含有二氧化碳的轻烃气体中选择性除去硫化氢和硫化羰的方法
  • 申请号: US914400
    申请日: 1986-10-02
  • 公开(公告)号: US4749555A
    公开(公告)日: 1988-06-07
  • 发明人: Warren V. Bush
  • 申请人: Warren V. Bush
  • 申请人地址: TX Houston
  • 专利权人: Shell Oil Company
  • 当前专利权人: Shell Oil Company
  • 当前专利权人地址: TX Houston
  • 主分类号: B01D53/14
  • IPC分类号: B01D53/14 C01B3/52 C01B17/16 C07C7/11 C10K1/14 C10L3/10
Process for the selective removal of hydrogen sulphide and carbonyl
sulfide from light hydrocarbon gases containing carbon dioxide
摘要:
The invention here disclosed is a process for the selective removal of H.sub.2 S and COS from a gas stream having a relatively large concentration of CO.sub.2 and being predominantly formed of light hydrocarbons, such as methane. This process provides for the selective solvent extraction of H.sub.2 S and COS without absorbing CO.sub.2. In this process, the solvent comprises a bridgehead amine, a tertiary amine, water, and optionally a physical solvent acceptable to COS absorption, such as sulfolane. The absorption conditions of this process comprise a pressure of from about atmospheric to about 1200 psig and a temperature of from about 40.degree. F. to about 250.degree. F. The treated stream derived from this process contains CO.sub.2 and light hydrocarbons and a near absence of H.sub.2 S and COS.
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