Process for removing carbon dioxide from gas mixtures
    6.
    发明申请
    Process for removing carbon dioxide from gas mixtures 有权
    从气体混合物中除去二氧化碳的方法

    公开(公告)号:US20050166756A1

    公开(公告)日:2005-08-04

    申请号:US10501240

    申请日:2003-01-14

    CPC classification number: B01D53/1493 Y02C10/06

    Abstract: The present invention relates to a process for removing carbon dioxide and optionally hydrogen sulphide and/or COS from a gas stream containing these compounds by washing the gas with an aqueous washing solution containing water, sulfolane and a secondary or tertiary amine derived from ethanolamine. More particularly the invention relates to the process described above, the process being carried out in the presence of a primary or secondary amine compound in an amount between 0.5 and 15 wt. % based on water, sulfolane and amine. The invention further relates to an absorbent liquid to be used in the above process.

    Abstract translation: 本发明涉及一种从含有这些化合物的气流中除去二氧化碳和任选的硫化氢和/或COS的方法,该方法是用含有水,环丁砜和衍生自乙醇胺的仲胺或叔胺的水洗涤溶液洗涤气体。 更具体地说,本发明涉及上述方法,该方法在原料​​或仲胺化合物的存在下进行,其量为0.5-15wt。 %,基于水,环丁砜和胺。 本发明还涉及在上述方法中使用的吸收剂液体。

    Process for the selective removal of inorganic and/or organic sulfur
compounds
    7.
    发明授权
    Process for the selective removal of inorganic and/or organic sulfur compounds 失效
    选择性去除无机和/或有机硫化合物的方法

    公开(公告)号:US5413627A

    公开(公告)日:1995-05-09

    申请号:US34798

    申请日:1993-03-01

    CPC classification number: B01D53/14 B01D53/1425 B01D53/1493 C10K1/14

    Abstract: For the selective removal of sulfur from gases, a physical scrubbing agent is used, comprising a heterocycle having five or more ring atoms, which contains two heteroatoms, one of which is nitrogen and the other of which is oxygen or nitrogen; and the heteroatoms in the rings of even member number of atoms occupy; one of the positions from 1,2 to 1,n/2 and, in the rings of uneven member number of atoms occupy one of the positions from 1,2 up to 1, (n-1)/2. Further, the nitrogen heteroatom(s) present in the ring is/are either double bonded or single bonded but, if single bonded, the nitrogen is organo-substituted.

    Abstract translation: 为了从气体中选择性除去硫,使用物理洗涤剂,其包含具有五个或更多个环原子的杂环,其含有两个杂原子,其中一个是氮,另一个是氧或氮; 并且偶数个原子的环中的杂原子占据; 位置从1,2到1,n / 2之一,并且在不均匀成员数原子的环中占据从1,2到1,(n-1)/ 2的位置之一。 此外,存在于环中的氮杂原子是双键或单键的,但如果单键键合,则氮被有机取代。

    Process for absorption of sulfur compounds from fluids
    8.
    发明授权
    Process for absorption of sulfur compounds from fluids 失效
    从流体中吸收硫化合物的工艺

    公开(公告)号:US5342593A

    公开(公告)日:1994-08-30

    申请号:US927584

    申请日:1992-08-10

    CPC classification number: B01D53/1493 B01D53/507 C10K1/14

    Abstract: Sulfur dioxide is removed from a fluid containing SO.sub.2 by employing as an absorbent therefor an aqueous solution of compound represented by Formula I: ##STR1## wherein X is --O--, --NR.sup.1 --, or --N.dbd.; each Y is independently --(CR.sup.2.sub.2)--, --(C.dbd.O)--, --O--, --NR.sup.1 --, --N.dbd., or --C(R.sup.2).dbd.; each R.sup.1 or R.sup.2 is independently hydrogen; an alkyl group; a hydroxyalkyl group; an aldehyde group; a carboxylic acid or salt group; or an alkyl group containing an aldehyde group, a carboxylic acid or salt group, ketone, carboxylic ester, ether, or sulfoxide group; and m is an integer preferably of from 2 to about 4. The absorbent solution preferably can be thermally regenerated by heating to remove SO.sub.2.

    Abstract translation: 通过使用式I表示的化合物的水溶液作为吸收剂从含有SO 2的流体中除去二氧化硫:-N =; 每个Y独立地为 - (CR22) - , - (C = O) - , - O - , - NR1 - , - N =或-C(R2) 每个R 1或R 2独立地是氢; 烷基; 羟基烷基; 醛基; 羧酸或盐基; 或含有醛基,羧酸或盐基的烷基,酮,羧酸酯,醚或亚砜基; m优选为2〜4的整数。吸收剂溶液优选通过加热热再生以除去SO 2。

    Process for the removal of NO from fluid streams using a water soluble
polymeric chelate of a polyvalent metal
    10.
    发明授权
    Process for the removal of NO from fluid streams using a water soluble polymeric chelate of a polyvalent metal 失效
    使用多价金属的水溶性聚合物螯合物从流体流中除去NO的方法

    公开(公告)号:US4778664A

    公开(公告)日:1988-10-18

    申请号:US15905

    申请日:1987-02-18

    CPC classification number: C10K1/125 B01D53/56 B01D53/60 C10K1/106 C10K1/14

    Abstract: The present invention relates to a cyclic continuous process and composition for the removal of NO and SO.sub.2 from a variety of fluid streams. A fluid stream containing NO and SO.sub.2 is contacted with an aqueous solution of water-soluble organic polymeric chelate containing a polyvalent metal, e.g., Fe (II). The NO is catalytically absorbed and in the presence of SO.sub.2, the imidodisulfonate is formed. Optionally, a reducing agent, such as sodium hydrogen sulfide, is added to maintain the polyvalent metal in the reduced state. The process next includes removal of the imidodisulfonate formed. The separation of water and low molecular weight materials and products, e.g. molecular weight below 500, usually occurs by ultrafiltration or dialysis, with recycle and re-use of the polyvalent metal chelate.

    Abstract translation: 本发明涉及用于从各种流体流中除去NO和SO 2的循环连续方法和组合物。 含有NO和SO 2的流体物流与含有多价金属例如Fe(II)的水溶性有机聚合物螯合物的水溶液接触。 NO被催化吸收,并且在SO 2存在下,形成亚氨基二磺酸盐。 任选地,加入还原剂,例如硫化氢钠,以保持多价金属处于还原状态。 该方法接下来包括除去所形成的亚氨基二磺酸盐。 水和低分子量材料和产品的分离,例如 分子量低于500,通常通过超滤或透析进行,再循环和重复使用多价金属螯合物。

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