发明授权
- 专利标题: Process for producing O,O-di-lower-alkylchlorothiophosphate
- 专利标题(中): O,O-二低级烷基氯代硫代磷酸酯的制备方法
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申请号: US11009申请日: 1987-02-05
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公开(公告)号: US4769494A公开(公告)日: 1988-09-06
- 发明人: Motomasa Ohsu , Koichi Kamemoto , Manabu Yahata , Tooru Tokumaru , Takeshi Hioki , Hiroshi Ueda
- 申请人: Motomasa Ohsu , Koichi Kamemoto , Manabu Yahata , Tooru Tokumaru , Takeshi Hioki , Hiroshi Ueda
- 申请人地址: JPX Osaka
- 专利权人: Sumitomo Chemical Company, Limited
- 当前专利权人: Sumitomo Chemical Company, Limited
- 当前专利权人地址: JPX Osaka
- 优先权: JPX61-35569 19860220; JPX61-288576 19861202
- 主分类号: C07F9/20
- IPC分类号: C07F9/20 ; C07F9/02
摘要:
A continuous process for producing O,O-di-lower alkylchlorothiophosphate very important as an intermediate for organo-phosphate series agricultural chemicals which comprises continuously reacting phosphorus sulfochloride with a lower alcohol in the presence of caustic soda according to a multi-stage reaction form comprising from 3 to 8 stages in which the following conditions are satisfied:(1) The amounts of caustic soda and a lower alcohol used shall be from 2 to 2.2 moles and 10 moles or more, respectively, based on 1 mole of phosphorus sulfochloride.(2) Caustic soda, water and the lower alcohol shall be used as a caustic soda/water/lower alcohol solution, and besides the caustic soda concentration of the aqueous caustic soda in said solution shall be from 30.0 to 99.5 wt.%.(3) To the 1st reaction stage shall be continuously supplied the whole amount of phosphorus sulfochloride required and from 45 to 85 wt.% each of the amounts of caustic soda and the lower alcohol required; and to the 2nd and subsequent reaction stages shall be continuously supplied the residual caustic soda and lower alcohol in divided portions so that the substantial amounts supplied become successively small toward the final reaction stage.(4) The temperature of the reaction system shall be -5.degree. C. or lower.(5) The residence time in the reaction system shall be within 4 hours.
公开/授权文献
- USD352194S Table 公开/授权日:1994-11-08